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Pectin/Activated Carbon-Based Porous Microsphere for Pb2+ Adsorption: Characterization and Adsorption Behaviour

文献类型: 外文期刊

作者: Wang, Ri-si 1 ; Li, Ya 2 ; Shuai, Xi-xiang 1 ; Liang, Rui-hong 1 ; Chen, Jun 1 ; Liu, Cheng-mei 1 ;

作者机构: 1.Nanchang Univ, State Key Lab Food Sci & Technol, Nanchang 330047, Jiangxi, Peoples R China

2.Chinese Acad Trop Agr Sci, South Subtrop Crops Res Inst, Zhanjiang 524091, Peoples R China

关键词: pectin; activated carbon; microsphere; Pb2+; adsorption

期刊名称:POLYMERS ( 影响因子:4.329; 五年影响因子:4.493 )

ISSN:

年卷期: 2021 年 13 卷 15 期

页码:

收录情况: SCI

摘要: The development of effective heavy metal adsorbents has always been the goal of environmentalists. Pectin/activated carbon microspheres (P/ACs) were prepared through simple gelation without chemical crosslinking and utilized for adsorption of Pb2+. Scanning electron microscopy (SEM) revealed that the addition of activated carbon increased the porosity of the microsphere. Texture profile analysis showed good mechanical strength of P/ACs compared with original pectin microspheres. Kinetic studies found that the adsorption process followed a pseudo-second-order model, and the adsorption rate was controlled by film diffusion. Adsorption isotherms were described well by a Langmuir isotherm model, and the maximum adsorption capacity was estimated to be 279.33 mg/g. The P/ACs with the highest activated carbon (P/AC(2:3)) maintained a removal rate over 95.5% after 10 adsorption/desorption cycles. SEM-energy-dispersive X-ray spectrum and XPS analysis suggested a potential mechanism of adsorption are ion exchange between Pb2+ and Ca2+, electronic adsorption, formation of complexes, and physical adsorption of P/ACs. All the above results indicated the P/ACs may be a good candidate for the adsorption of Pb2+.

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