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Occurrence, potential sources, and ecological risks of traditional and novel organophosphate esters in facility agriculture soils: A case study in Beijing, China

文献类型： 外文期刊

作者： Zhao, Fang 1 ; Ping, Hua 1 ; Liu, Jing 1 ; Zhao, Tianyu 1 ; Wang, Yingjun 1 ; Cui, Guanglu 3 ; Ha, Xuejiao 3 ; Ma, Zhihong 1 ; Li, Cheng 1 ;

作者机构： 1.Beijing Acad Agr & Forestry Sci, Inst Qual Stand & Testing Technol, Beijing 100097, Peoples R China

2.Minist Agr & Rural Affairs, Risk Assessment Lab Agroprod Beijing, Beijing, Peoples R China

3.Daxing Dist Planting Technol Promot Stn, Beijing 102600, Peoples R China

关键词： Organophosphate ester; Farmland soil; Mulch film; Risk assessment

期刊名称：SCIENCE OF THE TOTAL ENVIRONMENT （ 影响因子：9.8； 五年影响因子：9.6 ）

ISSN： 0048-9697

年卷期： 2024 年 923 卷

页码：

收录情况： SCI

摘要： Although traditional organophosphate esters (OPEs) in soils have attracted widespread interest, there is little information on novel OPEs (NOPEs), especially in facility agriculture soils. In this work, we surveyed 11 traditional OPEs, four NOPEs, and four corresponding organophosphite antioxidant precursors (OPAs) for the NOPEs in soil samples collected from facility greenhouses and open fields. The median summed concentrations of traditional OPEs and NOPEs were 14.1 mu g/kg (range: 5.38 - 115 mu g/kg) and 702 mu g/kg (range: 348 - 1952 mu g/kg), respectively, in film -mulched soils from greenhouses. These concentrations were much higher than those in soils without mulch films, which suggests that OPEs in soils are associated with plastic mulch films. Tris(2,4-di- tert - butylphenyl) phosphate, which is a NOPE produced by oxidation of (2,4-di- tert -butylphenyl) phosphite, was the predominant congener in farmland soils, with concentrations several orders of magnitude greater than those of traditional OPEs. Comparisons of OPEs in different mulch films and the corresponding mulched soils revealed that degradable and black films caused more severe pollution than polyethylene and white films. Traditional OPEs, including tris(2-ethylhexyl) phosphate and tricresyl phosphate, exhibited moderate risks in farmland soils, especially in film -mulched soils. NOPEs, including trisnonylphenol phosphate, posed high ecological risks to the terrestrial ecosystem. Risk evaluations should be conducted for a broad range of NOPEs in the environment.

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