Water-stable Al-TCPP MOF nanosheets with hierarchical porous structure for removal of chlorantraniliprole in water
文献类型： 外文期刊
作者： Xiao, Yawen 1 ; Chen, Chen 1 ; Wu, Yangli 1 ; Wang, Jiao 2 ; Yin, Yutao 1 ; Chen, Jianbing 3 ; Huang, Xiao 1 ; Qi, Peipei 2 ;
作者机构： 1.Nanjing Tech Univ, Key Lab Flexible Elect & Inst Adv Mat, 30 South Puzhu Rd, Nanjing 211816, Peoples R China
2.Zhejiang Acad Agr Sci, Inst Agr Prod Safety & Nutr, State Key Lab Managing Biot & Chem Threats Qual &, Hangzhou 310021, Peoples R China
3.Chizhou Univ, Sch Mat & Environm Engn, Chizhou 247000, Peoples R China
关键词： Al-TCPP nanosheets; Water-stable; Hierarchical porous structures; Adsorption; Chlorantraniliprole
期刊名称：MICROPOROUS AND MESOPOROUS MATERIALS （ 影响因子：5.455； 五年影响因子：4.862 ）
ISSN： 1387-1811
年卷期： 2021 年 324 卷
页码：
收录情况： SCI
摘要： The present work described the construction of a highly-efficient and stable adsorbent for removing hazardous pesticide from water. Water-stable metal-organic framework (MOF) nanosheets with three-dimensional (3D) structure, named as Al-TCPP nanosheets, were fabricated using aluminum (III) chloride hexahydrate and tetrakis (4-carboxyphenyl) porphyrin as the monomers with the assistance of a cetyltrimethylammonium bromide. Al-TCPP nanosheets and bulk crystals were comprehensively characterized to explore their differences in morphologies, microstructures and porous properties. Al-TCPP nanosheets kept the original crystal structure with an average thickness of similar to 17 nm. They also displayed excellent hydrophilic property, water stability and hierarchical porous structure with the surface area of 1359 m(2) g(-1), which were beneficial to the adsorption of chlorantraniliprole. Adsorption experiments were carried out and the maximum adsorption capacity of chlor-antraniliprole on Al-TCPP nanosheets achieved 371.91 mg g(-1), which was obviously higher than that of the bulk crystals (222.11 mg g(-1)). The disparity should be attributed to the hierarchical porous structures and highly exposed active sites of nanosheets. These results illuminate that MOF nanosheets can be a promising material for the adsorption of hazardous contaminants in water treatment.
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