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Effect of zinc oxide induced metal-ligand crosslink on the mechanical properties in the ethylene acrylic elastomer (AEM)

文献类型： 外文期刊

作者： Gao, Tianming 1 ; Na, Bokgyun 1 ; Choi, Hyoungjin 2 ; Chung, Kyungho 1 ;

作者机构： 1.Univ Suwon, Dept Polymer Engn, Hwaseong Si 445743, Gyeonggi Do, South Korea

2.Inha Univ, Dept Polymer Sci & Engn, Incheon 402751, South Korea

3.Chinese Acad Trop Agr Sci, Agr Prod Proc Res Inst, Zhanjiang 524001, Peoples R China

关键词： Ethylene acrylic elastomer (AEM);Zinc oxide;Amine;Mechanical properties;Dynamic properties;Metal-ligand crosslink

期刊名称：MATERIALS LETTERS （ 影响因子：3.423； 五年影响因子：3.003 ）

ISSN： 0167-577X

年卷期： 2018 年 214 卷

页码：

收录情况： SCI

摘要： The metal-ligand complex (sacrificial bonds) that exist in the mussels, bone and silk can dissipate energy and reinforce mechanical strength. Inspired by the high performance of metal-ligand complex, we introduced a kind of metal-ligand crosslink into the rubber network. In this work, ethylene acrylic elastomer (AEM) was filled with ZnO, and was cured by the amine cure system. The metal-ligand crosslink structure was verified by FTIR and XPS, and the tensile strength and dynamic properties were examined with a universal testing machine and rubber process analyzer (RPA). The results showed that coordination crosslink formed in the AEM matrix and exhibited outstanding tensile strength and unexpected dynamic properties due to the coordination bonds between Zn2+ and amine group. (C) 2017 Elsevier B.V. All rights reserved.

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