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Natural rubber/tetra-needle-like zinc oxide whisker composites: their preparation and characterization

文献类型： 外文期刊

作者： Chen, Xi 1 ; Hu, Zhibiao 1 ; Zhang, Fuquan 2 ; Zhang, Zhusen 1 ;

作者机构： 1.Longyan Univ, Coll Chem & Mat Sci, Longyan 364000, Fujian, Peoples R China

2.Chinese Acad Trop Agr Sci, Chinese Agr Minist, Key Lab Trop Crop Prod Proc, Agr Prod Proc Res Inst, Zhanjiang 524001, Peoples R China

关键词： composites;natural rubber;tetra-needle-like zinc oxide whiskers

期刊名称：JOURNAL OF POLYMER ENGINEERING （ 影响因子：1.367； 五年影响因子：1.433 ）

ISSN： 0334-6447

年卷期： 2018 年 38 卷 1 期

页码：

收录情况： SCI

摘要： Tetra-needle-like zinc oxide whiskers (T-ZnOw) were modified by Si69, and natural rubber (NR)/Si69-T-ZnOw composites were developed by latex-compounding techniques. The mechanical properties, morphology, cross-link density, and thermogravimetry of the composites were investigated. The results show that the tetra-needles of T-ZnOw tightly insert into the rubber matrix. T-ZnOw, which have a special four-dimensional structure, act as a skeleton in the rubber matrix. In comparison with the host NR, the mechanical properties, cross-link density, and thermostability of the resulting composites were significantly improved at Si69-T-ZnOw loadings of 4 wt%. During the thermal decomposition, various characteristic temperatures of the NR/Si69-T-ZnOw composites increase 5-9 degrees C over those of the pure NR. The NR/Si69-T-ZnOw composites have great potential to manufacture medical protective products with high performances.

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