文献类型: 外文期刊
作者: Wang, Yihong 1 ; Wei, Xiaoyi 2 ; Li, Jihua 2 ; Wang, Fei 2 ; Wang, Qinghuang 2 ; Chen, Jiacui 2 ; Kong, Lingxue 4 ;
作者机构: 1.Huazhong Agr Univ, Coll Food Sci & Technol, Wuhan 430070, Peoples R China
2.Chinese Acad Trop Agr Sci, Agr Prod Proc Res Inst, Zhanjiang 524001, Peoples R China
3.Natl Ctr Important Trop Crops Engn & Technol Rese, Haikou 571101, Peoples R China
4.Deakin Univ, Inst Frontier Mat, Geelong, Vic 3216, Australia
关键词: Nanocellulose;High pressure homogenization;Homogeneous isolation;Hydrogen bonds;[Bmim]Cl
期刊名称:FIBERS AND POLYMERS ( 影响因子:2.153; 五年影响因子:2.259 )
ISSN: 1229-9197
年卷期: 2015 年 16 卷 3 期
页码:
收录情况: SCI
摘要: Nanocellulose from cotton cellulose was prepared by high pressure homogenization (HPH) in ionic liquids (1-butyl-3-methylimidazolium chloride ([Bmim]Cl). The nanocellulose possessed narrow particle size distribution, with diameter range of 10-20 nm. Weight average molecular weight ((M) over bar (w)) of nanocellulose treated by HPH was lower (173.8 kDa) than the one ILs treated cellulose (344.6 kDa). X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), and Solid-state CP/MAS C-13 NMR measurements were employed to study the mechanism of structural changes, which suggested that network structure between cellulose chains were destructed by the shearing forces of HPH in combination with ionic liquids. The intermolecular and intra-molecular hydrogen bonds of cellulose were further destroyed, leading to the long cellulose molecular chains being collapsed into short chains. Therefore, the nanocellulose could provide desired properties, such as lower thermal stability and strong water holding capacity. Results indicated that it had great potential in the applications for packaging, medicines, cosmetics and tissue engineering.
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