Preparation and Structural Characterization of Hydroxylethyl Methacrylate Grafted Natural Rubber Latex
文献类型: 外文期刊
作者: Wei, Feiyun 1 ; Yu, Heping 1 ; Zeng, Zongqiang 1 ; Liu, Hongchao 1 ; Wang, Qifang 1 ; Wang, Jianlong 2 ; Li, Sidong 3 ;
作者机构: 1.Chinese Acad Trop Agr Sci, Agr Prod Proc Res Inst, Key Lab Trop Crop Prod Proc, Agr Minist, Zhanjiang 524001, Guangdong, Peoples R China
2.North Univ China, Sch Chem Engn & Environm, Taiyuan, Shanxi, Peoples R China
3.Guangdong Ocean Univ, Fac Sci, Zhanjiang, Peoples R China
关键词: Natural rubber latex;graft copolymerization;2-hydroxyethyl methacrylate;redox initiator system;hydrophilicity and blood compatibility
期刊名称:POLIMEROS-CIENCIA E TECNOLOGIA ( 影响因子:1.492; 五年影响因子:1.886 )
ISSN: 0104-1428
年卷期: 2014 年 24 卷 3 期
页码:
收录情况: SCI
摘要: The graft copolymer with semi-interpenetrating polymer networks (semi-IPNs) from 2-hydroxyethyl methacrylate (HEMA) and natural rubber (NR) latex was prepared using cumene hydroperoxide and tetraethylene pentamine redox initiator system. The changes of grafting ratios and grafting efficiency with the reaction time and temperature, the concentration of crosslinking agent, initiator and monomer were investigated. The appropriate amounts of crosslinking agent (0.1phr), initiator (0.2phr) and monomer (20phr) and the optimum reaction conditions of 16 degrees Cx8h were determined. The swelling temperature and times of monomers against NR latex particles were found to be significant for the grafting copolymerization and the appropriate swelling conditions were 16 degrees Cx20h. The water contact angle measurement and platelet adhesion evaluation indicated that the hydrophilicity and blood compatibility of NR latex could be improved by grafting copolymerization with HEMA.
- 相关文献
作者其他论文 更多>>
-
Reliable and continuous interfacial solar evaporation system with synergetic effects of photothermal and photoluminescence for full-day desalination
作者:Li, Lefan;Li, Tuanzhang;Guo, Jingyuan;Li, Chengpeng;Hu, Zhang;Li, Sidong;Li, Chengyong;Zhao, Pengfei;Li, Chengyong
关键词:
-
Rheological analysis of network structure of raw natural rubber prepared by different processing techniques
作者:Wang, Rui;Liao, Lusheng;Zhao, Pengfei;Yu, Heping;Zhang, Fuquan;Li, Gaorong;Peng, Zheng;Wang, Rui;Liao, Lusheng;Peng, Zheng
关键词:Raw natural rubber; Rheological behaviors; Network structure; Coagulation technique; Drying method
-
Effect of Proteins on the Vulcanized Natural Rubber Crosslinking Network Structure and Mechanical Properties
作者:Wang, Yueqiong;Su, Shiqi;Liu, Hongchao;Wang, Rui;Liao, Lusheng;Peng, Zheng;Li, Jihua;Wang, Yueqiong;Wu, Haijun;He, Dongning
关键词:natural rubber; proteins; crosslinked network structure; mechanical properties
-
Performance of Moringa Oil as an Effective Bioplasticizer on Static and Dynamic Mechanical Properties of Natural Rubber Vulcanizates
作者:Jarnthong, Methakarn;Li, Yongzhen;Yu, Heping;Wang, Rui;Wang, Yueqiong;Liu, Hongchao;Liao, Lusheng;Peng, Zheng;Lopattananon, Natinee;Peng, Zheng
关键词:Moringa oil; Natural rubber; Bioplasticizer; Static properties; Dynamic mechanical properties; Vulcanizates
-
Photothermal Ti2O3/polyurethane/polyacrylamide foam with high solar-evaporation efficiency
作者:Li, Lefan;Hu, Zhang;Wang, Di;Li, Sidong;Li, Chengpeng;Zhao, Pengfei;Wang, Zhifen;Zhang, Yucang
关键词:Photothermal material; Solar desalination; Dititanium trioxide; Liquified chitin
-
Strengthened adipic acid cross-linked epoxidized natural rubber by cellulose nanocrystals
作者:Yang, Xueli;Yang, Li;Xu, Chuanhui;Yang, Xueli;Yang, Li;Teng, Xiaodan;Xu, Chuanhui;Yang, Xueli;Yang, Li;Teng, Xiaodan;Xu, Chuanhui;Wang, Qifang;Wang, Yueqiong;Xu, Chuanhui
关键词:Epoxidized natural rubber; Cellulose nanocrystals; Mechanical reinforcement; Biobased
-
Research of strain induced crystallization and tensile properties of vulcanized natural rubber based on crosslink densities
作者:Wang, Yueqiong;Liao, Lusheng;Wang, Rui;Yu, Heping;Lian, Yujia;Liu, Hongchao;Peng, Zheng;Wang, Yueqiong;Lian, Yujia;Luo, Mingchao;Liao, Shuangquan;Zheng, Tingting;Wang, Yueqiong;Liao, Lusheng;Wang, Rui;Yu, Heping;Liu, Hongchao;Peng, Zheng
关键词:Crosslink density; Vulcanized natural rubber; Crystallization



