文献类型： 外文期刊
作者： Liao, Lu-Sheng 1 ; Liao, Jian-He 2 ; Li, Yi-Min 3 ; Chen, Yong-Ping 4 ; Zhao, Yan-Fang 4 ; He, Can-Zhong 1 ;
作者机构： 1.Hainan Univ, Coll Agr, Haikou 570228, Peoples R China
2.Hainan Univ, Coll Appl Sci & Technol, Danzhou 571737, Peoples R China
3.Hainan Policy & Ind Res Inst Low Carbon Econ, Haikou 570228, Peoples R China
4.Hainan Univ, Coll Mat & Chem Engn, Haikou 570228, Peoples R China
5.Chinese Acad Trop Agr Sci, Agr Prod Proc Res Inst, Zhanjiang 524001, Peoples R China
期刊名称：RUBBER CHEMISTRY AND TECHNOLOGY （ 影响因子：1.868； 五年影响因子：2.117 ）
ISSN： 0035-9475
年卷期： 2014 年 87 卷 1 期
页码：
收录情况： SCI
摘要： Microwave energy at a frequency of 2.45 GHz was used to coagulate natural rubber (NR) latex. Testing on technological properties indicates that microwave coagulation is a useful means of obtaining standard NR, meeting the requirements for technically specified rubber (TSR) 5, and Fourier transform infrared (FTIR) analysis indicates that NR coagulated using microwave radiation (NR-m) has higher levels of nitrogeneous compounds than NR coagulated using acid (NR-a). Curing behavior was characterized using a rheometer. Research on kinetics shows that the rate constants of the three periods of NR-m vulcanization (the induction period, the fast-cross-linking period, and the end stage of curing period) are higher than those of NR-a. The fast-cross-linking period of NR-m vulcanization can be divided into two stages (I and II) with two rate constants, K-2 and K-3, whereas for NR-a there is only one rate constant, K-2. With a change in curing temperature, the reaction orders for stages land II vary in the range 0.8-1.0, and K-2 and K-3 increase linearly with the increase in temperature, giving the activation energies E-2= 89.5 kJ/mol and E-3 = 115.3 kJ/mol.
- 相关文献
作者其他论文 更多>>
-
Revealing the Structure-Property Difference of Natural Rubber Prepared by Different Methods: Protein and Gel Content are Key Factors
作者：Huang, Shao-Qi;Zhang, Jun-Qi;Zhu, Yong;Kong, Ling-Min;Xie, Zheng-Tian;Wu, Jin-Rong;Liao, Lu-Sheng;Zhang, Fu-Quan
关键词：Natural rubber; Processing method; Protein; Gel content; Property
-
Efficient purification of bioethanol by an ethanol-trapping coordination network
作者：Li, Guo-Bi;Chen, Jing;Pan, Rong-Kai;Liu, Sheng-Gui;Song, Bai-Qiao;Zhang, Xin;Guan, Guo-Wei;Yang, Qing-Yuan;Zhang, Zhong;Pei, Ling-Min;Liao, Lu-Sheng;Wang, Jian
关键词：Naphthalene diimide; Ethanol-trapping adsorbent; Ethanol/water separation; Coordination networks; Metal-organic framework
-
Anions effect construction of 1D naphthalene diimide supramolecular chains by pi interactions and fluorescence detect iodide anion
作者：Li, Guo-Bi;Pan, Rong-Kai;Liu, Sheng-Gui;Liao, Lu-Sheng;Liao, Lu-Sheng;Zhang, Zhong
关键词：Supramolecular structural diversity; Naphthalene diimide; Fluorescence detection
-
A Robust Self-healing Polyurethane Elastomer Enabled by Tuning the Molecular Mobility and Phase Morphology through Disulfide Bonds
作者：Wu, Hai-Tao;Jin, Bi-Qiang;Wang, Hao;Wu, Wen-Qiang;Cao, Zhen-Xing;Yuan, Zhao-Yang;Huang, Yue;Li, Wei-Hang;Huang, Guang-Su;Wu, Jin-Rong;Liao, Lu-Sheng
关键词：Self-healing; Polyurethane; Disulfide bonds; Chain mobility; Phase morphology
-
Novel nonammonia preservative for concentrated natural rubber latex
作者：Wang, Ting;Zhang, Wen-Fei;Zhang, Ke-Xi;Wang, Ting;Gui, Hong-Xing;Zhang, Wen-Fei;Yu, Wei-Qiang;Li, Yi-Min;Huang, Mao-Fang;Zeng, Ri-Zhong
关键词：applications;crosslinking;film;mechanical properties;rubber
-
Thermal and Thermo-oxidative Degradations of Deproteinized Natural Rubber and Natural Rubber
作者：He, Can-zhong;Peng, Zheng;She, Xiao-dong;Luo, Yong-yue;He, Can-zhong;Liao, Shuang-quan;She, Xiao-dong;Tan, Hai-sheng;Zhong, Jie-ping
关键词：Deproteinized Natural Rubber;Thermo-oxidative degradation;Thermal degradation;Apparent activation energies
-
Thermo-oxidative Degradation of Natural Rubber Coagulated by Microorganisms
作者：Li, Si-Dong;Zhong, Jie-Ping;Yang, Lei;Liao, Shuang-Quan;She, Xiao-Dong;He, Can-Zhong
关键词：Microorganism;Natural rubber;Thermo-oxidative degradation;Protein content
