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Influence of incorporation sequence of silica nanoparticles on morphology, crystallization behavior, mechanical properties, and thermal resistance of melt blended thermoplastic natural rubber

文献类型： 外文期刊

作者： Jarnthong, Methakarn 1 ; Nakason, Charoen 1 ; Lopattananon, Natinee 1 ; Peng, Zheng 2 ;

作者机构： 1.Prince Songkla Univ, Fac Sci & Technol, Dept Rubber Technol & Polymer Sci, Pattani 94000, Thailand

2.Chinese Acad Trop Agr Sci, Agr Prod Proc Res Inst, Minist Agr, Key Lab Trop Crop Prod Proc, Zhanjiang 524001, Peoples R China

期刊名称：POLYMER COMPOSITES （ 影响因子：3.171； 五年影响因子：2.877 ）

ISSN： 0272-8397

年卷期： 2012 年 33 卷 11 期

页码：

收录情况： SCI

摘要： Thermoplastic natural rubber nanocomposites based on epoxidized natural rubber (ENR) and polypropylene blends at a fixed blend ratio of 50/50 wt% reinforced with small amount (2.5 wt%) of nanosilica (SiO2) were prepared by melt-mixing through three different incorporation sequences in an internal mixer. The effects of incorporation techniques on morphology, crystallization behavior, mechanical properties, dynamic, rheological characteristics, and thermal resistance of thermoplastic natural rubber (TPNR) nanocomposites were investigated. It was found that the dispersion of nanosilica in TPNRs was significantly dependent on the incorporation sequence. In the case where SiO2 was premixed in ENR before blending with polypropylene (PP), the final morphology showed the good dispersion of SiO2 in ENR phase, while the SiO2 particles were localized near the PP interface when SiO2 was premixed the in PP first. Whereas, when the three components were simultaneously mixed, the SiO2 particles were mainly dispersed in the PP phase. It was also found that the improvements of Young's modulus, tensile strength, damping behavior, and thermal stability of TPNR nanocomposites were more pronounced when the SiO2 particles localized in ENR phase. By contrast, the presence of SiO2 particles in PP domain either near the interface or inside the PP phase affected the reduction in crystallinity of PP phase and showed a negative effect on mechanical properties due to the poor interface interaction between PP and SiO2 particles. POLYM. COMPOS., 33:19111920, 2012. (C) 2012 Society of Plastics Engineers

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