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Structure and Properties of Self-assembled Narural Rubber/Multi-walled Carbon Nanotube Composites

文献类型： 外文期刊

作者： Peng Zheng 1 ; Feng Chunfang 2 ; Luo Yongyue 1 ; Yi Zhifeng 2 ; Kong Lingxue 2 ;

作者机构： 1.Chinese Acad Trop Agr Sci, Agr Prod Proc Res Inst, Key Lab Trop Crop Prod Proc, Chinese Agr Minist, Zhanjiang 524001, Peoples R China

2.Deakin Univ, Ctr Mat & Fiber Innovat, Inst Technol Res Innovat, Geelong, Vic 3217, Australia

关键词： natural rubber (NR);multi-walled carbon nanotube (MWCNTs);composites;latex compounding;self-assembly

期刊名称：JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION （ 影响因子：0.957； 五年影响因子：0.959 ）

ISSN： 1000-2413

年卷期： 2011 年 26 卷 5 期

页码：

收录情况： SCI

摘要： Natural rubber (NR)/multi-walled carbon nanotube (MWCNTs) composites were prepared by combining self-assembly and latex compounding techniques. The acid-treated MWCNTs (H(2)SO(4): HNO(3)=3:1, volume ratio) were self-assembled with poly (diallyldimethylammonium chloride) (PDDA) through electrostatic adhesion. In the second assembling, NR/MWCNTs composites were developed by mixing MWCNTs/PDDA solution with NR latex. The results show that MWCNTs arc homogenously distributed throughout the NR matrix as single tube and present a great interfacial adhesion with NR phase when MWCNTs contents are less than 3 wt%. Moreover, the addition of the MWCNTs brings about the remarkable enhancement in tensile strength and crosslink density compared with the NR host, and the data peak at 2 wt% MWCNTs loadings. When more MWCNTs are loaded, aggregations of MWCNTs are gradually generated, and the tensile strength and crosslink both decrease to a certain extent.

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