Enantioselective Synthesis of the Active Sex Pheromone Components of the Female Lichen Moth, Lyclene dharma dharma, and Their Enantiomers
文献类型： 外文期刊
第一作者： Zhou, Yun
作者： Zhou, Yun;Zhang, Yueru;Fu, Xiaochen;Xie, Hongqing;Han, Jinlong;Zhang, Jianhua;Shan, Chenggang;Wang, Jianan;Zhong, Jiangchun
作者机构：
关键词： sex pheromone; Lyclene dharma dharma; Evans' chiral auxiliary; enantioselective synthesis
期刊名称：MOLECULES （ 影响因子：4.2； 五年影响因子：4.6 ）
ISSN：
年卷期： 2024 年 29 卷 12 期
页码：
收录情况： SCI
摘要： The Lichen moth, Lyclene dharma dharma (Arctiidae, Lithosiinae), plays a significant role in forest ecosystem dynamics. A concise and novel method to synthesize the active sex pheromone components, (S)-14-methyloctadecan-2-one ((S)-1), (S)-6-methyloctadecan-2-one ((S)-2), and their enantiomers has been developed. Key steps in the synthesis include the use of Evans' chiral auxiliaries, Grignard cross-coupling reactions, hydroboration-oxidation, and Wacker oxidation. The synthesized sex pheromone components hold potential value for studies on communication mechanisms, species identification, and ecological management.
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