Residue behaviors and dietary risk of cyazofamid in turnip, onion and romaine lettuce assessed by a QuEChERS-LC-MS/MS methods

文献类型： 外文期刊

第一作者： Li, Ruijuan

作者： Li, Ruijuan;Li, Rumei;Liu, Tongjin;Liang, Hui;Fang, Feng;Men, Xue;Wang, Yongli;Sun-Waterhouse, Dongxiao

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关键词： Cyazofamid residue; Minor crops; Maximum residue limit; Dissipation; Dietary risk assessment

期刊名称：FOOD SCIENCE AND HUMAN WELLNESS （ 影响因子：7.0； 五年影响因子：8.3 ）

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年卷期： 2023 年 12 卷 5 期

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收录情况： SCI

摘要： In this study, the dissipation, terminal residues and dietary risk of the cyazofamid residue in three globally consumed minor crops, turnip (Brassica rapa L.), onion (Allium cepa L.) and romaine lettuce (Lactuca sativa L.) were assessed by supervised field trials at 6 locations of China in 2020. A reliable QuEChERS-LC-MS/MS method was developed for simultaneous analysis of cyazofamid and its primary metabolite, 4-chloro-5-p-tolylimidazole-2-carbonitrile (CCIM). The average recoveries of cyazofamid and CCIM in turnip, onion and romaine lettuce were 79%-97% and 77%-99%, respectively. The half-lives of cyazofamid in these crops were 5.7-6.5, 5.3-8.7 and 5.8-6.5 days in turnip, onion and romaine lettuce, respectively, with the final cyazofamid residues at harvest all lower than limit of quantitation (LOQ, 0.01 mg/kg). The turnip roots, onion bulbs and romaine lettuce leaves grown in China under Good Agricultural Practices conditions and harvested 10, 14 and 5 days, respectively, after the cyazofamid SC (100 g/L) application, would be reasonably safe for consumption by the general population. The maximum residue limit (MRL) values of cyazofamid could be tentatively set as 10 mg/kg for turnip leaves, 0.3 mg/kg for turnip roots, 0.05 mg/kg for onion bulbs, and 10 mg/kg for romaine lettuce leaves.(c) 2023 Beijing Academy of Food Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).

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