Monocarboxylate-driven structural growth in Calix[n]arene-polyoxotitanate hybrid systems: utility in hydrogen production from water

文献类型: 外文期刊

第一作者: Yang, Xin-Xue

作者: Yang, Xin-Xue;Yi, Xiao-Yi;Liu, Chao;Yu, Wei-Dong;Li, Lei-Jiao

作者机构:

期刊名称:CHEMICAL COMMUNICATIONS ( 影响因子:6.222; 五年影响因子:6.008 )

ISSN: 1359-7345

年卷期: 2020 年 56 卷 90 期

页码:

收录情况: SCI

摘要: A carboxylate-driven assembly strategy has been developed for the first time to build calix[n]arene-based polyoxotitanate clusters with tuneable nuclearity and structures. Photocatalytic studies revealed that these clusters exhibit structural-dependent H-2 evolution ability with a maximum rate up to 415.11 mu mol h(-1) g(-1), which is almost the highest recorded in polyoxotitanate clusters.

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