One-pot self-assembly synthesis of Ni-doped ordered mesoporous carbon for quantitative hydrogenation of furfural to furfuryl alcohol

文献类型： 外文期刊

第一作者： Tang, Yiwei

作者： Tang, Yiwei;Qiu, Mo;Yang, Jirui;Shen, Feng;Wang, Xiaoqi;Qi, Xinhua;Qi, Xinhua

作者机构：

期刊名称：GREEN CHEMISTRY （ 影响因子：9.48； 五年影响因子：9.707 ）

ISSN： 1463-9262

年卷期： 2021 年 23 卷 4 期

页码：

收录情况： SCI

摘要： Ni-Doped ordered mesoporous carbon (Ni@OMC) was prepared by a one-pot solvent evaporation-induced self-assembly (EISA) process with sustainable biomass-derived gallic acid as the carbon precursor, F127 as the soft template and Ni2+ as the cross-linker and catalytically active ingredient. Ni particles with ca. 7.8 nm diameter were uniformly dispersed in the carbon skeleton of the synthesized OMC due to the confinement effects of Ni particles in the carbon skeleton of OMC by coordination between gallic acid molecules and metal Ni2+ ions in the EISA process. The as-synthesized Ni@OMC sample showed excellent catalytic performance for the hydrogenation of biomass-derived furfural into furfuryl alcohol (FFA), and a FFA yield as high as 98% could be achieved at 180 degrees C in 4 h reaction time in 1-propanol solvent in the presence of 3 MPa H-2 pressure. The prepared Ni@OMC exhibited good stability and recyclability. This work provides a green and simple one-pot strategy for the synthesis of metal-doped OMCs without using harmful phenolic and formaldehyde compounds, which should have many applications in fields such as catalysis, drug delivery and energy storage.

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