Investigation of non-thermal atmospheric plasma for the degradation of avermectin solution

文献类型： 外文期刊

第一作者： LV, Yue

作者： LV, Yue;ZOU, Liang;WANG, Xiaolong;SUN, Ying;ZHAO, Tong;ZHANG, Yuantao;LI, Huidong;CEHN, Zilei;FANG, Liping

作者机构：

关键词： non-thermal atmospheric plasma; pesticide degradation; avermectins; molecular dynamics simulation

期刊名称：PLASMA SCIENCE & TECHNOLOGY （ 影响因子：1.358； 五年影响因子：1.157 ）

ISSN： 1009-0630

年卷期： 2021 年 23 卷 5 期

页码：

收录情况： SCI

摘要： Increasing concern with regard to food safety in the presence of pesticide residues (PRs) on the surface of agricultural products has resulted in the rapid development of practical degrading technologies for corresponding PRs. In this paper, an unconventional method of degrading pesticides, non-thermal atmospheric plasma (NTAP), was proposed to degrade the avermectin (AVM) in aqueous solution. Optical emission spectroscopy shows that NTAP, consisting of filamentary streamers, contains a variety of reactive oxygen species (ROS) that may interact with AVM. The high-performance liquid chromatography (HPLC)-MS/MS results indicate that the efficiency of AVM degradation seriously depends on multiple operation parameters of the NTAP, including the applied voltage, treatment time and gas flow rate. The maximum degradation rate of AVM was observed to be 97.47% after 240 s exposure under NTAP with an applied voltage of 18 kV and gas flow rate of 1 l min(-1). Molecular dynamics simulation based on a reactive force field for the interaction between O (ground state atomic oxygen) and AVM was performed to analyze the underpinning mechanisms. The simulation result shows the possible pathways of the NTAP-generated O degrading AVM by destroying the glycosyl group or fracturing the ester group.

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