Magnetic Solid-Phase Extraction of Pyrethroid Pesticides from Environmental Water Samples Using Deep Eutectic Solvent-type Surfactant Modified Magnetic Zeolitic Imidazolate Framework-8

文献类型： 外文期刊

第一作者： Liu, Huifang

作者： Liu, Huifang;Jiang, Lihua;Lu, Meng;Li, Tengfei;Liu, Huifang;Lu, Meng;Liu, Guangyang;Xu, Xiaomin;Li, Lingyun;Lin, Huan;Lv, Jun;Huang, Xiaodong;Xu, Donghui

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关键词： magnetic solid-phase extraction; zeolitic imidazolate framework; deep eutectic solvents; pyrethroids; environmental water

期刊名称：MOLECULES （ 影响因子：4.411； 五年影响因子：4.587 ）

ISSN：

年卷期： 2019 年 24 卷 22 期

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收录情况： SCI

摘要： A simple, sensitive and effective magnetic solid-phase extraction (MSPE) technique was developed for the extraction of pyrethroid pesticides from environmental water samples, followed by gas chromatography tandem triple quadrupole mass spectrometry determination. An adsorbent of magnetic zeolitic imidazolate framework-8@deep eutectic solvent (M-ZIF-8@DES) was prepared using deep eutectic solvent coated on the surface of M-ZIF-8. The features of M-ZIF-8@DES were confirmed by material characterizations, and the results indicated that M-ZIF-8@DES has a good magnetism (61.3 emu g(-1)), a decent surface area (96.83 m(2) g(-1)) and pore volume (0.292 mL g(-1)). Single factor experiments were carried out to investigate the effect of different conditions on the performance of MSPE. Under the optimal conditions, the developed method performs good linearity (R-2 >= 0.9916) in the concentration range of 1-500 mu g L-1. The limits of detection were in the range of 0.05-0.21 mu g L-1 (signal/noise = 3/1). The intraday relative standard deviation (RSD) and interday RSD were less than 9.40%. Finally, the proposed technique was applied for the determination of pyrethroid pesticides in environmental water samples. This work shows the potential of DES-modified metal-organic frameworks for different sample pretreatment techniques.

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