Formation mechanism of aroma compounds in a glutathione-glucose reaction with fat or oxidized fat

文献类型: 外文期刊

第一作者: Zhao, Jian

作者: Zhao, Jian;Wang, Tianze;Xie, Jianchun;Xiao, Qunfei;Chen, Feng;Sun, Baoguo;Cheng, Jie;Wang, Shi;Chen, Feng

作者机构:

关键词: Glutathione; [C-13(6)]-D-glucose; Fat; Meat flavor; Formation pathway; Lipid degradation; Maillard reaction; Interaction

期刊名称:FOOD CHEMISTRY ( 影响因子:7.514; 五年影响因子:7.516 )

ISSN: 0308-8146

年卷期: 2019 年 270 卷

页码:

收录情况: SCI

摘要: Glutathione and glucose with or without chicken fat/oxidized chicken fat were thermally reacted for generation of stewed meat-like aroma, where 42 sulfur-containing odorants were identified by gas chromatography-mass spectrometry (GC-MS) and gas chromatography-olfactometry (GC-O). The observed effects or interactions on meat flavor formation due to the fats were similar to previous reports of cysteine-reducing sugar reactions. Carbohydrate module labeling approach demonstrated ten alkyl chain compounds were indeed resulted from the lipid degradation-Maillard reaction interactions, whereas the fats had little effect on formation pathways of compounds only derived from the Maillard reaction. Formation pathways of 26 potent aroma compounds were proposed, particularly, involving two benzene derivatives and seven complex thiophenes. Notably, it was found for the first time just 2-ethylthiophene could result from both an intact skeleton of glucose and the lipid degradation product of 2,4-hexadienal, and the carbohydrate modules methylglyoxal and hydroxyacetone could arise from the glutamic acid of GSH.

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