Simultaneous determination of broflanilide and its metabolites in five typical Chinese soils by a modified quick, easy, cheap, effective, rugged, and safe method with ultra high performance liquid chromatography and tandem mass spectrometry

文献类型： 外文期刊

第一作者： Xu, Jun

作者： Xu, Jun;Dong, Fengshou;Liu, Xingang;Wu, Xiaohu;Wang, Ran;Zheng, Yongquan

作者机构：

关键词： broflanilide; metabolites; residue analysis; soil

期刊名称：JOURNAL OF SEPARATION SCIENCE （ 影响因子：3.645； 五年影响因子：2.943 ）

ISSN： 1615-9306

年卷期： 2018 年 41 卷 24 期

页码：

收录情况： SCI

摘要： An efficient and sensitive analytical method for simultaneous determination of trace amounts of a new insecticide broflanilide and its metabolites (S(PFH-OH)-8007 and DM-8007) residues in five typical Chinese soils (red soil, black soil, fluvo-aquic soil, cinnamon soil and paddy soil) was developed. The samples were prepared by a modified quick, easy, cheap, effective, rugged, and safe method. The determination of broflanilide and its metabolites was conducted by ultra high performance liquid chromatography with tandem mass spectrometry with an electrospray ionization source in the positive ion mode. This is the first report for the determination of broflanilide and its metabolites in different soils. Broflanilide and its metabolites were extracted from all soils with acetonitrile and purified by a mixture of primary secondary amine and graphitized carbon black. The average recoveries of the three compounds in five types of soil ranged from 85.3 to 111.8% and the relative standard deviations were less than 13.6%. The limit of quantification was 0.1 mu g/kg for all three compounds. This method was successfully used to determine broflanilide and its metabolites in five types of soil. The method was validated to be simple and effective for the determination of trace residual broflanilide and its metabolites in five types of soil.

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