Loading of MgO onto Fe-rich sludge-derived Fe0 biochar composites for efficient aqueous Pb2+removal: Performance and mechanism

文献类型: 外文期刊

第一作者: Zhang, Qi

作者: Zhang, Qi;Xiao, Wendan;Chen, De;Zhao, Shouping;Zhao, Zhen;Ye, Xuezhu;Huang, Xiaolei;Zhang, Qi;Xiao, Wendan;Chen, De;Zhao, Shouping;Zhao, Zhen;Ye, Xuezhu;Huang, Xiaolei;Zhang, Qi;Xiao, Wendan;Chen, De;Zhao, Shouping;Zhao, Zhen;Ye, Xuezhu;Huang, Xiaolei;Li, Hui

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关键词: Zero-valent iron; Magnesium oxide; Biochar; Removal; Pb2+

期刊名称:JOURNAL OF WATER PROCESS ENGINEERING ( 影响因子:6.7; 五年影响因子:6.7 )

ISSN: 2214-7144

年卷期: 2025 年 69 卷

页码:

收录情况: SCI

摘要: Scavenging of Pb from aquatic environments is of great importance to environmental and human health. Although Fe0 biochar composites (Fe0@BCs) possess high Pb2+ adsorption capacities, they have high fabrication costs and relatively low stability. Here, a novel MgO-modified Fe0@BCs was successfully fabricated by copyrolyzing Fe-rich sludge (FRS) and MgCl2 at 900 degrees C. The Fe0@BC obtained at an FRS:MgCl2 mass ratio of 10.0:2.7 (MBC-2.7) displayed significantly higher performance than unmodified Fe0@BC. MgO loading effectively prevented the formation of Pb0-Fe0 bimetallic systems, thereby reducing the Fe ions and maintaining the pH of the solution. The enhanced ion-exchange capacity due to modification was also correlated with the Pb2+ removal capacity. Moreover, MBC-2.7 primarily removed Pb2+ through chemisorption, with a maximum scavenging capacity of 439.23 mg/g. The removal mechanisms mainly involved adsorption, reduction of Pb2+ to Pb0, ion exchange, and precipitation. Overall, Fe0@BCs after proper modification with MgO presented great promise for use in the remediation of Pb contamination.

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