A pyrylium salt-based fluorescent probe for the highly sensitive detection of methylamine vapour

文献类型: 外文期刊

第一作者: Yin, Wenzhu

作者: Yin, Wenzhu;Deng, Bihua;Ma, Fang;Zhang, Jinqiu;Zhou, Mingxu;Wang, Haiyang;Lu, Yu;Yin, Wenzhu;Deng, Bihua;Ma, Fang;Zhang, Jinqiu;Zhou, Mingxu;Wang, Haiyang;Lu, Yu;Wang, Hongjin

作者机构:

期刊名称:ANALYST ( 影响因子:5.227; 五年影响因子:4.793 )

ISSN: 0003-2654

年卷期: 2022 年 147 卷 15 期

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收录情况: SCI

摘要: The amine vapour produced by microorganisms is an important indicator of food spoilage. Amines are also ubiquitous in the chemical industry. The development of molecule-based ion sensors has been a pivotal issue that is currently receiving considerable attention. In this work, a new pyrylium salt-based fluorescent probe MTPY has been developed as a rapid, highly sensitive, and selective sensor for methylamine vapour. MTPY exhibits an obvious fluorescence response from yellow to cyan towards CH3NH2 vapour. The calibration curve of titration analysis shows a linear relationship of the fluorescence intensity at 514 nm versus the methylamine concentration in the range of 0.1-2 ppm. In addition to the linearity (R-2 = 0.974) and short response time with a low detection limit (2.6 ppt, 8.4 x 10(-8) M), the sensing mechanism was traced using mass spectrometry.

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