Syntheses and characterizations of zinc(II) and copper(II) complexes with reduced Schiff base derived from salicylaldehyde and D,L-selenomethionine

文献类型： 外文期刊

第一作者： Wang, Ling-Yun

作者： Wang, Ling-Yun;Ran, Xue-Guang;Cao, De-Rong;Ran, Xue-Guang;Hao, Jie

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关键词： Reduced Schiff base;D;L-Selenomethionine;Metal complexes;Single-crystal X-ray structure

期刊名称：JOURNAL OF COORDINATION CHEMISTRY （ 影响因子：1.751； 五年影响因子：1.462 ）

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收录情况： SCI

摘要： New zinc(II) and copper(II) complexes with a reduced Schiff-base ligand derived from D,L-selenomethionine and salicylaldehyde have been synthesized and characterized by elemental analysis, magnetic susceptibility, IR, and NMR measurements. The single-crystal X-ray structure of the Cu(II) complex reveals that this complex is a carboxylate-bridged dimer of dinuclear copper(II) subunits and all metal centers are five-coordinate with O4N donor sets in distorted square-pyramidal geometries. The Cu(II) complex consists of a 1-D coordination polymer.

分类号： O61

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