Effects of copper and aluminum on the adsorption of sulfathiazole and tylosin on peat and soil

文献类型： 外文期刊

第一作者： Pei, Zhiguo

作者： Pei, Zhiguo;Yang, Shuang;Li, Chunmei;Zhang, Shuzhen;Shan, Xiao-quan;Wen, Bei;Guo, Baoyuan;Li, Lingyun

作者机构：

关键词： Adsorption;Copper;Aluminum;Sulfathiazole;Tylosin

期刊名称：ENVIRONMENTAL POLLUTION （ 影响因子：8.071； 五年影响因子：8.35 ）

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收录情况： SCI

摘要： Effects of copper (Cu) and aluminum (Al) on the adsorption of sulfathiazole (STZ) and tylosin (T) to peat and soil were investigated using a batch equilibration method. Results show that Cu suppressed STZ adsorption onto peat and soil at pH ＜ 5.0 because of the electrostatic competition, while increased STZ adsorption at pH ＞ 5.0 due to the formation of STZ-Cu complexes and/or Cu bridge. In contrast, Al only decreased STZ adsorption at pH ＜ 6.0, and exerted slight effect on STZ adsorption at ＞6.0. As for T, both Cu and Al suppressed its adsorption over the entire pH range owing to three reasons: 1) electrostatic competition between Cu/Al and T~+; 2) Cu/Al adsorption made the soil and peat surface less negatively charged, which was unfavorable for T~+ adsorption; 3) the shrunken pore size of peat and soil retarded the diffusion of large-sized T into these pores.

分类号： X5

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