Modification of D-pi-A chromophore for the improvement of solubility in water

文献类型: 外文期刊

第一作者: Ouyang Canbin

作者: Ouyang Canbin;Cao, Aocheng;Li, Xiaobing

作者机构:

关键词: Chromophore;Second order nonlinear optics;Multi hydroxyl;Water solubility;Optical materials;Optoelectronics materials

期刊名称:MATERIALS LETTERS ( 影响因子:3.423; 五年影响因子:3.003 )

ISSN:

年卷期:

页码:

收录情况: SCI

摘要: In order to explore the application of organic D-pi-A molecules in bio-imaging, novel D-pi-A molecule (chromophore OY) with multi-hydroxyl groups was designed and synthesized. Compared to the traditional D-pi-A molecule, chromophore OY showed us great improvement in water solubility. The solubility of chromophore OY in water could reach 200 ppm. Else, the thermal stability of chromophore OY was also studied. Due to the presence of multi-hydroxyl groups, the thermal stability of chromophore OY was not very good. The initial decomposition temperature was just above 100 degrees C, which was attributed to the dehydration of the hydroxyl groups. Though the SHG effect is not very high, it is large enough for the detection of SHG signal in water solution (0.2-0.3 pm/V). (C) 2015 Elsevier B.V. All rights reserved.

分类号: TB1`TB3

  • 相关文献

[1]Design and Synthesis of Novel Chromophore with Multi-Carboxyl Groups. Chen, Haiying,Ouyang, Canbin. 2018

[2]Luminescent and thermal properties of a novel red-emitting silicon fluoride acrylate-Eu(III) copolymer for white LEDs. Hu, Jun,Xu, Lin,Xie, Hongde,Xu, Lei,Tsuboi, Taiju,Huang, Wei,Tsuboi, Taiju,Huang, Wei. 2014

[3]Synthesis and optical properties of D-pi-A chromophore with double carboxyl groups. Ouyang Canbin,Cao, Aocheng,Li, Xiaobing.

[4]Introduction of N atom into the conjunction system of organic second order nonlinear optical chromophores: An effective method for improving the photochemistry stability. Zhou, Jian,Wang, Min,Li, Xiaobing.

[5]Preparation of Main-Chain Polymers Based on Novel Monomers with D-pi-A Structure for Application in Organic Second-Order Nonlinear Optical Materials with Good Long-Term Stability. Li, Yuan,Yan, Dongdong,Wane, Qiuxia,Guo, Meixia,Cao, Aocheng,Liu, Jialei,Liu, Qi. 2017

[6]Transfer Rates of 19 Typical Pesticides and the Relationship with Their Physicochemical Property. Chen, Hongping,Pan, Rong,Zhang, Minglu,Liu, Xin,Lu, Chengyin,Chen, Hongping,Pan, Meiling,Liu, Xin,Lu, Chengyin,Chen, Hongping,Liu, Xin,Lu, Chengyin.

[7]Inclusion of quinestrol and 2,6-di-O-methyl-beta-cyclodextrin: Preparation, characterization, and inclusion mode. Ouyang, Can-Bin,Liu, Xiao-Hui,Liu, Qi,Yuan, Hao-Liang. 2013

[8]Inclusion complexation of chloropropham with beta-cyclodextrin: Preparation, characterization and molecular modeling. Ge, Xia,He, Jiang,Qi, Fengming,Yang, Ying,Lu, Ruihua,Huang, Lizhen,Ge, Xia,Huang, Zheng. 2011

作者其他论文 更多>>