Perfect recycle and mechanistic role of hydrogen sulfate ionic liquids as additive in ethanol for efficient conversion of carbohydrates into 5-ethoxymethylfurfural

文献类型： 外文期刊

第一作者： Guo, Haixin

作者： Guo, Haixin;Aida, Taku M.;Smith, Richard Lee, Jr.;Qi, Xinhua;Duereh, Alif;Hiraga, Yuya;Smith, Richard Lee, Jr.

作者机构：

关键词： Biomass inulin;Biofuel;Reactivation;Reuse of homogeneous catalyst;Reaction mechanism

期刊名称：CHEMICAL ENGINEERING JOURNAL （ 影响因子：13.273； 五年影响因子：11.529 ）

ISSN：

年卷期：

页码：

收录情况： SCI

摘要： Hydrogen sulfate ionic liquid as co-solvent and homogeneous catalyst can promote efficient conversion of carbohydrates into 5-ethoxymethylfurfural (5-EMF). Yields of 5-EMF were as high as 77% and 43% from inulin and sucrose, respectively, in the mixed solvent system of ethanol-[BMIM][HSO(4)1 for 30 min reaction time at 130 degrees C. The ionic liquid could be perfectly recycled with a single pretreatment of activated carbon for 24 h. Based on the characterization with H-1 NMR and ATR-FTIR, the mechanism for the hydrogen sulfate ionic liquid promoted conversion of inulin into 5-EMF through stabilization of 5-hydroxymethylfurfural (5-HMF) with the C-2 hydrogen of the ionic liquid. Hydrogen sulfate ionic liquid as additive allows efficient conversion of carbohydrates into biofuels and as homogeneous catalysts, they can be easily reactivated and recycled with activated carbon treatment. (C) 2017 Elsevier B.V. All rights reserved.

分类号： TQ

  • 相关文献

[1]Biofuel from Microalgae: Current Status, Opportunity and Challenge. Wang, Hui,Liu Yuhuan,Ruan, Roger,Ruan, Roger,Liu, Guangxian. 2014

[2]Oxidation of a non-phenolic lignin model compound by two Irpex lacteus manganese peroxidases: evidence for implication of carboxylate and radicals. Qin, Xing,Zhang, Xiaoyu,Qin, Xing,Sun, Xianhua,Huang, Huoqing,Bai, Yingguo,Wang, Yuan,Luo, Huiying,Yao, Bin,Su, Xiaoyun. 2017

[3]Co-downregulation of the hydroxycinnamoyl-CoA:shikimate hydroxycinnamoyl transferase and coumarate 3-hydroxylase significantly increases cellulose content in transgenic alfalfa (Medicago sativa L.). Tong, Zongyong,Li, Heng,Zhang, Rongxue,Ma, Lei,Dong, Jiangli,Wang, Tao,Tong, Zongyong,Wang, Tao.

[4]Efficient conversion of fructose into 5-ethoxymethylfurfural with hydrogen sulfate ionic liquids as co-solvent and catalyst. Guo, Haixin,Aida, Taku M.,Smith, Richard Lee, Jr.,Qi, Xinhua,Hiraga, Yuya,Smith, Richard Lee, Jr..

[5]Zymomonas mobilis: a novel platform for future biorefineries. He, Ming Xiong,Wu, Bo,Qin, Han,Tan, Fu Rong,Wang, Jing Li,Shui, Zong Xia,Dai, Li Chun,Zhu, Qi Li,Pan, Ke,Tang, Xiao Yu,Wang, Wen Guo,Hu, Qi Chun,He, Ming Xiong,Hu, Qi Chun,Ruan, Zhi Yong. 2014

[6]Estimation of un-used land potential for biofuels development in (the) People's Republic of China. Tian, Yishui,Zhao, Lixin,Meng, Haibo,Sun, Liying,Tian, Yishui,Yan, Jinyue,Yan, Jinyue.

[7]Metabolic engineering of 2-phenylethanol pathway producing fragrance chemical and reducing lignin in Arabidopsis. Qi, Guang,Wang, Dian,Yu, Li,Tang, Xianfeng,Chai, Guohua,He, Guo,Ma, Wenxuan,Li, Shengying,Fu, Chunxiang,Zhou, Gongke,Qi, Guang,Wang, Dian,Yu, Li,Tang, Xianfeng,Chai, Guohua,He, Guo,Ma, Wenxuan,Li, Shengying,Fu, Chunxiang,Zhou, Gongke,Kong, Yingzhen,Wang, Dian,Tang, Xianfeng.

[8]Cell wall polysaccharide distribution in Miscanthus lutarioriparius stem using immuno-detection. Cao, Yingping,Li, Junling,Yu, Li,Chai, Guohua,He, Guo,Hu, Ruibo,Qi, Guang,Fu, Chunxiang,Zhou, Gongke,Kong, Yingzhen. 2014

[9]Genetic diversity in tetraploid switchgrass revealed by AFLP marker polymorphisms. Todd, J.,Wu, Y. Q.,Wang, Z.,Samuels, T.,Wang, Z.. 2011

作者其他论文 更多>>

微信小程序