Synthesis and Insecticidal Activity of N-tert-Butyl-N,N '-diacylhydrazines Containing 1,2,3-Thiadiazoles

文献类型： 外文期刊

第一作者： Wang, Huan

作者： Wang, Huan;Yang, Zhikun;Fan, Zhijin;Mi, Na;Wang, Shouxin;Zhang, Zhengcai;Song, Haibin;Wu, Qingjun;Zhang, Youjun;Liu, Feng

作者机构：

关键词： 4-Methyl-1,2,3-thiadiazole;diacylhydrazine;Insect growth regulator

期刊名称：JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY （ 影响因子：5.279； 五年影响因子：5.269 ）

ISSN： 0021-8561

年卷期： 2011 年 59 卷 2 期

页码：

收录情况： SCI

摘要： N-tert-Butyl-N,N'-diacylhydrazines are nonsteroidal ecdysone agonists used as environmental benign pest regulators. In this paper, two series of new N-tert-butyl-N,N'-diacylhydrazine derivatives containing 1,2,3-thiadiazole were designed and synthesized. All structures of the synthesized compounds were confirmed by proton nuclear magnetic resonance ((1)H NMR), infrared spectroscopy (IR), and high-resolution mass spectrometry (HRMS). Bioasssay results indicated that most of the synthesized compounds possessed good insecticidal activities against Plutella xylostella L. and Culex pipiens pallens as compared with the positive control, tebufenozide. The results of this study indicated that 1,2,3-thiadiazoles, as an important active substructure, could improve or maintain the activity of the dicylhydrazines and favor novel pesticide development.

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