An efficient synthetic method of 11,12-dihydroxyl eudesmanolide sesquiterpenoid from alpha-santonin
文献类型: 外文期刊
第一作者: Li, DR
作者: Li, DR;Tu, YQ;Cao, AC
作者机构:
关键词: introduction;tertiary hydroxyl;rearrangement-oxidation
期刊名称:CHINESE CHEMICAL LETTERS ( 影响因子:6.779; 五年影响因子:4.558 )
ISSN: 1001-8417
年卷期: 2001 年 12 卷 1 期
页码:
收录情况: SCI
摘要: A short and efficient procedure fbr introduction of tertiary hydrosyl to C-11 of eudesmanolide based on the rearrangement-oxidation of the exocylic double bond has been developed, which is synthetically valuable for a series of natural eudesmanolide sesquiterpenoids containing the 11,12-diol.
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A facile construction of eudesmanolide denebutenolide via SMI(2)-catalyzed rearrangement of an enol ester epoxide
作者:Li, D;Shi, L;Cao, AC;Tu, YQ
关键词:construction;alpha,beta-unsaturated lactone;catalyzed-rearrangement