A facile construction of eudesmanolide denebutenolide via SMI(2)-catalyzed rearrangement of an enol ester epoxide

文献类型： 外文期刊

第一作者： Li, D

作者： Li, D;Shi, L;Cao, AC;Tu, YQ

作者机构：

关键词： construction;alpha,beta-unsaturated lactone;catalyzed-rearrangement

期刊名称：CHINESE CHEMICAL LETTERS （ 影响因子：6.779； 五年影响因子：4.558 ）

ISSN： 1001-8417

年卷期： 2002 年 13 卷 2 期

页码：

收录情况： SCI

摘要： A very convenient construction procedure of the alpha, beta-unsaturated lactone has been carried out in 98% yield. Sml(2) (10%) was used as catalyst for rearrangement of an enol ester epoxide of eudesmanolide sesquiterpene. The possible mechanism was also discussed.

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