A novel bis-coumarin gelator W for the selective detection of Al3+and its biological application
文献类型: 外文期刊
第一作者: Zhang, Ying-Peng
作者: Zhang, Ying-Peng;Liang, Yu-Ning;Yang, Chen;Yang, Yun-Shang;Zhang, Ying-Peng;Liang, Yu-Ning;Yang, Chen;Yang, Yun-Shang;Guo, Hui-Chen;Guo, Hui-Chen;Zhang, Hong-Rui
作者机构:
关键词: Bis-coumarin; Organic gels; Aluminum ions; Self-assembly
期刊名称:JOURNAL OF MOLECULAR LIQUIDS ( 影响因子:6.0; 五年影响因子:5.6 )
ISSN: 0167-7322
年卷期: 2024 年 397 卷
页码:
收录情况: SCI
摘要: A novel bis-coumarin gelator W was designed and synthesized. The W has good gel behavior in ethanol, tertbutanol, and isopropanol solutions. The self-assembly mechanism of the W was investigated using techniques such as UV-Vis absorption spectroscopy, infrared spectroscopy, and XRD. The results show that the driving forces for gelation are: 7C -7C stacking, hydrogen bonding, and van der Waals forces, respectively. The effect of solvent on the gelation behavior is analyzed in the Teas plot, which shows that the solvent and the W can only form gels under the appropriate force. Through the optical performance test, the W can specifically recognize Al3+. The detection limit is as low as 7.32 x 10-7 M, the complexation constant is Ka = 1.033 x 103M-1. In addition, the cytotoxicity test of the two cell lines shows that their toxicity is low, which indicates that the W can be used in the field of bioengineering.
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