Surface properties and suspension stability of low-temperature pyrolyzed biochar nanoparticles: Effects of solution chemistry and feedstock sources

文献类型: 外文期刊

第一作者: Xu, Chen-Yang

作者: Xu, Chen-Yang;Li, Qi-Rui;Geng, Zeng-Chao;Xu, Chen-Yang;Geng, Zeng-Chao;Hu, Fei-Nan;Zhao, Shi-Wei;Hu, Fei-Nan;Zhao, Shi-Wei

作者机构:

关键词: Fruit tree branch biochar; Zeta potential; Critical coagulation concentration; Particle interaction

期刊名称:CHEMOSPHERE ( 影响因子:7.086; 五年影响因子:6.956 )

ISSN: 0045-6535

年卷期: 2020 年 259 卷

页码:

收录情况: SCI

摘要: Intensive application of biochar requires better understanding of their environmental behaviors such as stability, fate, and mobility. The release of bulk biochar into biochar nanoparticles (NPs) may bring risks because of their potential flowing into downstream water bodies with nutrients/containments attached. Low-temperature pyrolyzed biochars, namely fruit tree branch biochar of 350/450/550 degrees C (FB350, FB450 and FB550), corn straw biochar of 350 degrees C (CB350) and peanut straw biochar of 350 degrees C (PB350), were produced, and their NPs were extracted. The yield, elemental composition, mineral composition, surface functional groups and zeta potential of biochar NPs were characterized. Subsequently their suspension stability was evaluated in NaCl and CaCl2 solutions by dynamic light scattering technique. The Hamaker constants and particle interaction energy of the biochar NPs were calculated by adopting Derjaguin-Landau-Verwey-Overbeek theory. For biochar NPs of same feedstock, the stability of FB350/450/550-NPs could be predicted well by their zeta potential values. The types of their surface functional groups were the same while their adsorption intensity differed. The scenarios for biochar NPs of different feedstock sources were different, that is, inconsistent variation was observed between their zeta potential and suspension stability, which were rooted in the variable type and quantity of surface functional groups. In conclusion, feedstock was the most significant factor that influenced the suspension stability of biochar NPs, followed by the pyrolysis temperature and solution chemistry, which were highly dependent on surface potential. The findings provide references for the environmental risk evaluation of biochar NPs and reasonable application of biochar in field. (C) 2020 Elsevier Ltd. All rights reserved.

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