Enantioselective Synthesis of the Sex Pheromone of Sitodiplosis mosellana (Géhin) and Its Stereoisomers
文献类型: 外文期刊
第一作者: Wang, Jianan
作者: Wang, Jianan;Li, Xiaoyang;Bian, Qinghua;Zhong, Jiangchun;Zhou, Yun
作者机构:
关键词: orange wheat blossom midge; chiral source; sex pheromone; asymmetric synthesis
期刊名称:MOLECULES ( 影响因子:4.6; 五年影响因子:5.0 )
ISSN:
年卷期: 2025 年 30 卷 3 期
页码:
收录情况: SCI
摘要: (2S,7S)-2,7-Nonanediyl dibutyrate is the sex pheromone of Sitodiplosis mosellana (G & eacute;hin). In this study, this sex pheromone and its three stereoisomers were prepared. Central to this strategy was the ring opening of chiral epoxide with an alkynyllithium and the hydrogenation of the triple bond. Moreover, this approach consisted of six steps, and the total yields were 59-64%.
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