Asymmetric Synthesis of Three Alkenyl Epoxides: Crafting the Sex Pheromones of the Elm Spanworm and the Painted Apple Moth

文献类型： 外文期刊

第一作者： Zhou, Yun

作者： Zhou, Yun;Tian, Beijing;Zhu, Yanwei;Zhang, Yujuan;Han, Jinlong;Shan, Chenggang;Wang, Jianan;Zhong, Jiangchun

作者机构：

关键词： sex pheromone; alkenyl epoxides; elm spanworm; painted apple moth; asymmetric synthesis

期刊名称：MOLECULES （ 影响因子：4.6； 五年影响因子：4.9 ）

ISSN：

年卷期： 2024 年 29 卷 9 期

页码：

收录情况： SCI

摘要： A concise synthesis of the sex pheromones of elm spanworm as well as painted apple moth has been achieved. The key steps were the alkylation of acetylide ion, Sharpless asymmetric epoxidation and Brown's P2-Ni reduction. This approach provided the sex pheromone of the elm spanworm (1) in 31% total yield and those of the painted apple moth (2, 3) in 26% and 32% total yields. The ee values of three final products were up to 99%. The synthesized pheromones hold promising potential for use in the management and control of these pests.

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