Organic Porous Materials with Temperature Responsive Coatings for Mesosulfuron-Methyl Delivery
文献类型: 外文期刊
第一作者: Su, Wangcang
作者: Su, Wangcang;Niu, Yujia;Chen, Wenzhe;Sun, Lanlan;Xue, Fei;Xu, Hongle;Wu, Renhai;Yang, Aiguo;Zhao, Shirui
作者机构:
关键词:
temperature-controlled release; mesosulfuron-methyl;
期刊名称:JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY ( 影响因子:6.2; 五年影响因子:6.4 )
ISSN: 0021-8561
年卷期: 2025 年 73 卷 28 期
页码:
收录情况: SCI
摘要: To address the challenges of wheat phytotoxicity and herbicide resistance of conventional mesosulfuron-methyl (MES) formulations in controlling Aegilops tauschii, a temperature-responsive controlled-release herbicide system (MPA-TPA-POPs@MES@PLU) was developed in this study. MES was encapsulated within porous MPA-TPA-POPs and coated with thermosensitive Pluronic F-127 (PLU), enabling intelligent release regulated by temperature. Compared to MES, this system demonstrated superior sustained-release properties, reducing emissions by 62.7% at 3 degrees C while maintaining effective release at 25 degrees C. Biological evaluations revealed that the GR50 against A. tauschii was 28% lower than that of MES oil dispersion (OD). Notably, the formulation exhibited superior crop safety, reducing wheat phytotoxicity by 62% and 54% in fresh weight inhibition rate compared to MES OD and MES TC at 3 degrees C. By synergistically integrating porous carrier loading and thermoresponsive coating technologies, this study achieved precise temperature-modulated herbicide release, extending herbicidal persistence while minimizing nontarget crop exposure through environmental temperature perception, providing a paradigm for designing intelligent agrochemical delivery systems with high efficacy and biosafety.
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