Electrochemical cycloaddition of hydrazones with cyanamide for the synthesis of substituted 5-amine-1,2,4-triazoles

文献类型： 外文期刊

第一作者： Yang, Minghua

作者： Yang, Minghua;Tang, Dong;Jiang, Rui;Mu, Yangxiu;Hong, Yu;Wan, Yaya;Hou, Jing;Tang, Dong

作者机构：

期刊名称：CHEMICAL COMMUNICATIONS （ 影响因子：4.9； 五年影响因子：4.9 ）

ISSN： 1359-7345

年卷期： 2023 年 59 卷 16 期

页码：

收录情况： SCI

摘要： An eco-friendly and efficient electrochemical method for the synthesis of 5-amine-1,2,4-triazole derivatives has been developed by employing hydrazones or in situ generation of hydrazones with cyanamide using KI as the catalyst and electrolyte. This strategy could be smoothly conducted with simple reaction conditions at room temperature without the addition of a chemical oxidant in an undivided cell, and cyanamide has been proven to be of great value in electrosynthesis.

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