Triaqua(2,2 '-bipyridine-kappa(2)N,N ')(5-nitroisophthalato-kappa O(1))zinc(II) monohydrate
文献类型: 外文期刊
第一作者: Hao, Lujiang
作者: Hao, Lujiang;Liu, Xia
作者机构:
期刊名称:ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE ( 影响因子:0.347; 五年影响因子:0.278 )
ISSN: 1600-5368
年卷期: 2008 年 64 卷
页码:
收录情况: SCI
摘要: In the title compound, [Zn(C(8)H(3)NO(6))(C(10)H(8)N(2))(H(2)O)(3)]center dot H(2)O, the Zn(II) cation is hexacoordinated by a chelating 2,2'-bipyridine ligand, one carboxylate O atom from a 5-nitro-isophthalate dianion and three water molecules in a slightly distorted octahedral geometry. The structure contains isolated neutral complexes, in contrast to coordination polymers formed by Mn(II), Co(II) and Cu(II) with the same ligand set. An extensive network of hydrogen bonds is formed between the water molecules and the carboxylate groups.
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