catena-Poly[[[diacrylato-kappa(4)O,O '-neodymium(III)]-di-mu-acrylato-kappa(3)O,O ':O ';kappa(3)O:O,O '-[triaquaneodymium(III)]-di-mu-acrylato-kappa(3)O,O ':O ';kappa(3)O:O,O '] trihydrate]

文献类型： 外文期刊

第一作者： Hao, Lujiang

作者： Hao, Lujiang;Kong, Binbin;Mu, Chunhua

作者机构：

期刊名称：ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE （ 影响因子：0.347； 五年影响因子：0.278 ）

ISSN： 1600-5368

年卷期： 2008 年 64 卷

页码：

收录情况： SCI

摘要： The title compound, {[Nd(2)(CH(2)CHCOO)(6)(H(2)O)(3)]center dot 3H(2)O}(n), was synthesized by hydrothermal methods. The structure contains one-dimensional coordination polymers in which two distinct Nd(III) atoms show different coordination modes. One is coordinated by four bidentate acrylate ligands, two of which bridge Nd(III) atoms, and by two O atoms from a further two bridging acrylate ligands. The other Nd(III) atom is coordinated by two bidentate acrylate ligands, two O atoms from bridging acrylate ligands, and three water molecules. Extensive hydrogen bonding between the coordinated and uncoordinated water molecules and the O atoms of the acrylate ligands link the coordination polymers into a three-dimensional network.

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