Bis{mu-2,2 '-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}bis[(thiocyanato-kappa N)iron(III)]
文献类型： 外文期刊
第一作者： Hao, Lujiang
作者： Hao, Lujiang;Kong, Binbin;Mu, Chunhua
作者机构：
期刊名称：ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE （ 影响因子：0.347； 五年影响因子：0.278 ）
ISSN： 1600-5368
年卷期： 2008 年 64 卷
页码：
收录情况： SCI
摘要： The title compound, [Fe-2(C16H14N2O2)(2)(NCS)(2)], is isostructural with the Mn-III-containing analogue. Each Fe-III atom is chelated by a tetradentate 2,2'-[ethane-1,2-diylbis(nitrilomethylidyne)] diphenolate ligand and by the N atom of a thiocyanate anion, in a square-pyramidal arrangement. The complex molecules form centrosymmetric dimers, with an Fe-O contact of 2.549 (3) angstrom, trans to each thiocyanate anion, completing a distorted octahedral coordination geometry.
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