Can helical spring dextrin be composed of higher eight glucose units per turn?

文献类型: 外文期刊

第一作者: Xu, Jin

作者: Xu, Jin;Zhao, Wenxiu;Ning, Yawei;Bashari, Mohanad;Jin, Zhengyu;Duan, Xiang;Chen, Haiying;Wu, Fengfeng;Xu, Xueming;Xu, Baocai;Zhang, Lixia

作者机构:

关键词: Spring dextrin;Single-wall carbon nanotubes;Helical conformation

期刊名称:JOURNAL OF MOLECULAR STRUCTURE ( 影响因子:3.196; 五年影响因子:2.618 )

ISSN: 0022-2860

年卷期: 2013 年 1036 卷

页码:

收录情况: SCI

摘要: In this study, spring dextrin (SD) has been noncovalently wrapped onto single-wall carbon nanotubes (SWNTs) to explain the number of glucose residues per turn larger than eight. Differential scanning calorimetry (DSC), FR-IR and Raman spectroscopy demonstrated that SD formed supramolecular complex with SWNTs. Furthermore, Atomic force microscope (AFM) micrograph indicated that SD wrap around SWNTs into helical superstructures. Finally, molecular dynamic simulation suggested that the space of helix cavity changed with different diameter of SWNTs, and SD wrapped around SWNTs (1 nm, 1.5 nm and 2 nm) were 11, 14 and 17 glucose units per turn, respectively. (C) 2012 Elsevier B.V. All rights reserved.

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