Sorption of Atrazine in Tropical Soil by Biochar Prepared from Cassava Waste

文献类型: 外文期刊

第一作者: Deng, Hui

作者: Deng, Hui;Ge, Chengjun;Deng, Hui;Ge, Chengjun;Yu, Huamei;Chen, Miao

作者机构:

关键词: Sorption;Biochars;Cassava wastes;Atrazine;Paddy soil

期刊名称:BIORESOURCES ( 影响因子:1.614; 五年影响因子:1.923 )

ISSN: 1930-2126

年卷期: 2014 年 9 卷 4 期

页码:

收录情况: SCI

摘要: Biochar (BC) is a carbonaceous and porous product generated from the incomplete combustion of biomass and has been recognized as an efficient adsorbent. This study evaluated the ability of BC to sorb atrazine pesticide in tropical soil, and explored potential environmental values of BC on mitigating organic micro-pollutants. BC was produced from cassava waste via pyrolyzation under oxygen-limiting conditions at 350, 550, and 750 degrees C (MS350, MS550, and MS750, respectively). Three biochars were characterized and investigated as sorbents for the removal atrazine from tropical soil. BC pyrolyzed at higher temperatures more quickly reached equilibrium. The pseudo-second-order model perfectly simulated the sorption kinetics for atrazine with the coefficients R-2 above 0.996, and the sorption amount at equilibrium (q(e)) was 0.016 mg/g for MS350, 0.025 mg/g for MS550 and 0.050 mg/g for MS750. The isotherms of MS350 displayed relatively linear behavior, whereas the sorption of atrazine on MS550 and MS750 followed a nonlinear isotherm. The sorption data were well described by the Freundlich model with logK(F) of 0.476 for MS350, 0.771 for MS550, 1.865 for MS750. A thermodynamic study indicated that the sorption of atrazine in BC-added soil was a spontaneous and endothermic process and was primarily controlled by physisorption. In addition, lower pH was conducive to the sorption of atrazine in BC-added soil.

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