Effect of CMCS on Vulcanization Kinetics of Natural Rubber
文献类型: 外文期刊
第一作者: Wang Yongzhou
作者: Wang Yongzhou;Zeng Rizhong;Wang Yongzhou;Gui Hongxing;Chen Tao;Huang Honghai;Zhang Fuquan;Wang Yongzhou;Gui Hongxing;Chen Tao;Huang Honghai;Zhang Fuquan
作者机构:
关键词: natural rubber;kinetics;carboxymethyl chitosan;rate constant;activation energy
期刊名称:ADVANCED ENGINEERING MATERIALS II, PTS 1-3
ISSN: 1022-6680
年卷期: 2012 年 535-537 卷
页码:
收录情况: SCI
摘要: In this work, effect of carboxymethyl chitosan (CMCS) on vulcanization kinetics of natural rubber was studied using the Rheometer MDR2000. The results showed that both the rate constants of induction period and curing period of natural rubber (K-N) was greater than that of natural rubber added CMCS and the dosage is 0.05% of fresh latex (CMCS-1), but less than that of natural rubber added CMCS and the dosage is 0.1% of fresh latex (CMCS-2), and the activation energy 100.8kJ/mol of induction period of K-N is greater than the activation energy 96.7kJ/mol, 93.7kJ/mol of induction period of CMCS-1, CMCS-2, respectively and that the activation energy 104.4 kJ/mol of curing period of K-N is less than the activation energy111.9kJ/mol of curing period of CMCS-1, and bigger than the activation energy 103.4 of CMCS-2 at the same temperature.
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