Investigation of the formation mechanism of the pepper starch-piperine complex
文献类型: 外文期刊
第一作者: Zhao, Kangyun
作者: Zhao, Kangyun;Zhang, Siwei;Xu, Fei;Zhang, Yutong;Wang, Xu;Zhang, Jiyue;Zhang, Yanjun;Zhao, Kangyun;Zhang, Siwei;Xu, Fei;Zhang, Yutong;Wang, Xu;Zhang, Jiyue;Zhang, Yanjun;Zhao, Kangyun;Zhang, Siwei;Xu, Fei;Zhang, Yutong;Wang, Xu;Zhang, Jiyue;Zhang, Yanjun;Piao, Chunhong;You, Sang Guan
作者机构:
关键词: Piperine; Pepper starch; Porous starch; Interaction mechanism; Loading efficiency
期刊名称:INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES ( 影响因子:8.2; 五年影响因子:7.8 )
ISSN: 0141-8130
年卷期: 2024 年 268 卷
页码:
收录情况: SCI
摘要: In this study, a new carrier for loading piperine was prepared using pepper starch, and its interaction mechanism was investigated. The porous pepper starch-piperine complex (PPS-PIP) showed higher loading efficiency (76.15 %) compared to the porous corn starch-piperine complex (PCS-PIP (52.34 %)). This may be ascribed to the hemispherical shell structure of porous pepper starch (PPS) compared to the porous structure of porous corn starch (PCS) based on the SEM result. PPS-PIP had smaller particle size (10.53 mu m), higher relative crystallinity (38.95 %), and better thermal stability (87.45 degrees C) than PCS-PIP (17.37 mu m, 32.17 %, 74.35 degrees C). Fourier transform infrared spectroscopy (FTIR) results implied that piperine not only forms a complex with amylose but may also be physically present in porous starch. This was demonstrated by the short-range order and X-ray type. Molecular dynamics simulations confirmed that hydrogen bonding is the primary interaction between amylose and piperine. Besides the formation of the amylose-piperine complex, some of the piperine is also present in physical form.
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