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Two new sesquiterpene polyol esters from Celastrus angulatus

文献类型: 外文期刊

作者: Wei, Shao-Peng 1 ; Wu, Wen-Jun 1 ; Ji, Zhi-Qin 1 ; Zhang, Ji-Wen 2 ; Guo, Yong-Ze 3 ; Xue, Jian 4 ;

作者机构: 1.NW A&F Univ, Inst Pesticides, Yangling 712100, Shaanxi, Peoples R China

2.NW A&F Univ, Coll Sci, Yangling 712100, Shaanxi, Peoples R China

3.Tianjin Acad Agr Sci, Cent Lab, Tianjin 300381, Peoples R China

4.Chinese Acad Med Sci, Inst Med Plant Dev, Beijing 100193, Peoples R China

期刊名称:HELVETICA CHIMICA ACTA ( 影响因子:2.164; 五年影响因子:1.393 )

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收录情况: SCI

摘要: Two novel sesquiterpene polyol esters with a dihydro-β-agarofuran (=(3R,5aS,9R,9aS)-octahydro-2,2,5a,9-tetramethyl-2H-3,9a-methano-1-benzoxepin) skeleton, (1α,2α,4β,8α,9α)-1,2,8,12- tetrakis(acetyl-oxy)-9-(furoyloxy)-4-hydroxydihydro-β-agarofuran (1) and (1α,2α,6β,8α,9α)-1,2,6,8,12-pentakis(acetyl-oxy) -9-(benzoyloxy)dihydro-β-agarofuran (2), and the three known compounds (1α,2α,4β,6β,8α,9β)-1,2,6-tris(acetyloxy) -9-(benzoyloxy)-4-hydroxy-8,12-bis(isobutyryloxy)dihydro-β-agarofuran (3), (1α, 2α,4β,6β,8α,9β)-1,2,6,8- tetrakis(acetyloxy)-9-(furoyloxy)-4-hydroxy-12-isobutyryloxy) dihydro-β-agarofuran (4), and (1α,2α,4β,6β,8α, 9β)-1,2,6-tris(acetyloxy)-9-(benzoyloxy)-4-hydroxy-8-(isobutyryloxy) -12-[(2-methylbutanoyl)oxy]dihydro-β-agarofuran (5) were isolated from the root bark of Celastrus angulatus. Their chemical structures were elucidated by analyses of their MS and NMR data.

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