Group-selective molecularly imprinted polymer solid-phase extraction for the simultaneous determination of six sulfonamides in aquaculture products
文献类型： 外文期刊
作者： Shi, Xizhi 1 ; Meng, Yuan 1 ; Liu, Jinghua 1 ; Sun, Aili 1 ; Li, Dexiang 1 ; Yao, Chunxia 2 ; Lu, Yin 1 ; Chen, Jiong 1 ;
作者机构： 1.Ningbo Univ, Key Lab Appl Technol Marine Biol, Minist Educ, Fac Life Sci & Biotechnol, Ningbo 315211, Zhejiang, Peoples R China
2.Shanghai Acad Agr Sci, Inst Agrifood Stand & Testing Technol, Shanghai 201106, Peoples R China
关键词： Aquaculture products;Group selectivity;Molecularly imprinted polymers;Sulfonamides (SAs)
期刊名称：JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES （ 影响因子：3.205； 五年影响因子：3.068 ）
ISSN：
年卷期：
页码：
收录情况： SCI
摘要： Group-selective molecularly imprinted polymers (MIPs) made from sulfonamides (SAs) using functional monomer methacrylic acid (MAA) were synthesized. The derived molecularly imprinted solid-phase extraction (MISPE) cartridges were developed for the purification and enrichment of aquatic products. The optimum template molecule and the ratio of the functional monomer to the template for obtaining group selectivity to SAs were sulfadimethoxine (SDM) and 4:1, respectively. The MIPs were characterized by Brunauer-Emmett-Teller (BET), scatchard plot, and chromatography analysis, all of which demonstrate better chromatographic behavior and group-selectivity of MIPs for SAs compared with those of corresponding NIPs. The extraction conditions of MISPE for six SAs were optimized; the method precision and accuracy were satisfactory for the fish and shrimp samples at 0.05, 0.1, and 0.2mgkg~(-1) spiked levels. Recoveries ranging from 85.5% to 106.1% (RSD, 1.2-7.0%, n=3) were achieved. The limits of detection (S/N=3) and quantitation (S/N=10) in the shrimp and fish samples were achieved from 8.4 to 10.9μgkg~(-1) and from 22.4 to 27.7μgkg~(-1), respectively. Therefore, the obtained MIPs and MISPE can be employed for the enrichment and clean-up of SAs. This paper presents a new analytical method which enables the simultaneous determination and quantification of SAs in aquaculture products.
- 相关文献
作者其他论文 更多>>
-
A novel, low-cost, and efficient separation strategy based on S-doped C3N4 for the analysis of PCDD/Fs and dioxin-like PCBs
作者：Luo, Yanli;Luo, Yanli;Liu, Chengbin;Wang, Xianli;Zhang, Qicai;Yao, Chunxia;Huang, Di;Liu, Xing;Lu, Yangyang;Song, Wei;Chen, Shanshan;Zhou, Jiaxin;Rao, Qinxiong;Song, Weiguo;Liu, Chengbin;Wang, Xianli;Zhang, Qicai;Yao, Chunxia;Huang, Di;Liu, Xing;Lu, Yangyang;Song, Wei;Chen, Shanshan;Zhou, Jiaxin;Rao, Qinxiong;Liu, Chengbin;Wang, Xianli;Zhang, Qicai;Yao, Chunxia;Huang, Di;Liu, Xing;Lu, Yangyang;Song, Wei;Chen, Shanshan;Zhou, Jiaxin;Rao, Qinxiong
关键词：PCDD/Fs; Dl-PCBs; Carbon nitride; Separation; Analysis
-
2D/2D Ni-MOF/BiOCl S-scheme heterojunction with boosted charge transfer and photocatalytic degradation of tetracycline
作者：Zhou, Jiaxin;Yao, Chunxia;Song, Weiguo;Liu, Chengbin;Song, Wei;Tang, Huiling;Zhang, Zhijie
关键词：S-scheme heterojunction; Ni-MOF; BiOCl; Photocatalyst; Tetracycline
-
0D/3D heterostructure of perovskite Cs2CuBr4 quantum dots/Bi2O3 microflower as a step-scheme photocatalyst for enhanced CO2 reduction
作者：Tang, Huiling;Wang, Xuesheng;Zhang, Zhijie;Yao, Chunxia
关键词：Step-scheme photocatalyst; Cs2CuBr4; CO2 reduction; Charge transfer
-
Occurrence and Risk Assessment of Pesticides, Phthalates, and Heavy Metal Residues in Vegetables from Hydroponic and Conventional Cultivation
作者：Chen, Shanshan;Yao, Chunxia;Zhou, Jiaxin;Song, Weiguo;Ma, Haiyao;Jin, Jing;Kai, Zhenpeng
关键词：risk assessment; hydroponic; vegetable; pesticide residues; phthalates; heavy metals
-
Cs2 CuBr4 perovskite quantum dots confined in mesoporous CuO framework as a p-n type S-scheme heterojunction for efficient CO2 photoconversion
作者：Zhang, Zhijie;Li, Xun;Tang, Huiling;Tang, Huiling;Yao, Chunxia;Wu, Junhao;Li, Kui
关键词：Photocatalytic CO 2 conversion; Mesoporous CuO; Cs 2 CuBr 4; Perovskite quantum dots; S -scheme heterojunction
-
Gradual effects of gradient concentrations of perfluorooctane sulfonate on the antioxidant ability and gut microbiota of red claw crayfish ( Cherax quadricarinatus )
作者：Hong, Shuang;Song, Weiguo;Liu, Chengbin;Yao, Chunxia;Zhu, Chenxi;Han, Mingming;Jiang, Qichen;Lv, Weiwei;Jiang, Qichen;Hong, Shuang
关键词：Gut microbes; PFOS; Antioxidant response; Cherax quadricarinatus
-
Potential nervous threat of nanoplastics to Monopterus albus: Implications from a metabolomics study
作者：Yao, Chunxia;Liu, Chengbin;Hong, Shuang;Zhou, Jiaxin;Lv, Weiwei;Zhou, Wenzong;Yao, Chunxia;Liu, Chengbin;Zhou, Jiaxin;Hong, Shuang;Gao, Zhaoliang;Li, Yiming
关键词：Polystyrene nanoplastics; Metabolomics; M. albus; Liver; Neurotoxicity
