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Preparation and properties of starch-based polyurethane/montmorillonite composite coatings for controlled-release fertilizer

文献类型： 外文期刊

作者： Liao, Yun 1 ; Liu, Li 2 ; Wang, Meng 2 ; Li, Li-Xia 3 ; Cao, Bing 3 ; Wang, Hai 2 ; Huang, Wei-Qiang 2 ;

作者机构： 1.Univ South China, Sch Chem & Chem Engn, Hengyang, Peoples R China

2.Univ South China, Sch Nucl Sci & Technol, Hengyang 421001, Hunan, Peoples R China

3.Beijing Acad Agr & Forestry Sci, Inst Plant Nutr & Resource, Beijing 100097, Peoples R China

关键词： controlled‐ release fertilizer; montmorillonite; polyurethane; starch

期刊名称：POLYMER COMPOSITES （ 影响因子：3.171； 五年影响因子：2.877 ）

ISSN： 0272-8397

年卷期： 2021 年 42 卷 5 期

页码：

收录情况： SCI

摘要： In order to enhance the controlled-release property of starch-based polyurethane (SPU) coating, polyurethane/montmorillonite (SPU/MMT) composite coatings for controlled-release urea were prepared by in-situ polymerization with a rotating drum. The effect of MMT on morphology, structure, physico-chemical properties, especially controlled-release property of the as-prepared composite coatings were studied in detail. The results showed that MMT particles dispersed well in SPU matrix, and the obtained SPU/MMT composite coatings possessed more tough and compact morphology with less-visible holes compared with SPU coating. With the content of MMT rising to 3%, the time needed for 75% nitrogen release increased to 49 days, much longer than 14 days of SPU coating. Further, the nitrogen release mechanism underlying the structure and properties of SPU/MMT composite coatings were discussed and elucidated. According to the analysis, the superior controlled-release property of SPU/MMT coatings originated from the impermeablity to water molecules of layered MMT acting as mechanical barriers to increase the diffusion path and resistance, the enhanced crosslinking density and hydrophobicity of composite system due to the introduction of MMT, as well as the improved mechanical properties hindering the formation of cracks and enlargement of the holes on the surface of composite coatings.

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