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Morphology control of Cu and Cu2O through electrodeposition on conducting polymer electrodes

文献类型： 外文期刊

作者： Sun, Yan Chun 1 ; Sun, Chun Yu 2 ; Chen, Zhong Xiang 1 ; Wang, Peng 1 ; Wang, Hai Tao 1 ; Yao, Ming Zhu 1 ; Wu, Song 1 ;

作者机构： 1.Chinese Acad Fishery Sci, Minist Agr & Rural Areas, Heilongjiang River Fisheries Res Inst, Lab Qual & Safety Risk Assessment Aquat Prod Harb, Harbin 150070, Peoples R China

2.Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Peoples R China

3.Shanghai Ocean Univ, Coll Food Sci & Technol, Dept Food Sci & Engn, Shanghai 201306, Peoples R China

期刊名称：INORGANIC CHEMISTRY FRONTIERS （ 影响因子：5.958； 五年影响因子：5.792 ）

ISSN： 2052-1553

年卷期： 2021 年 8 卷 6 期

页码：

收录情况： SCI

摘要： Here, using a conducting polymer, polyaniline (PANI), membrane as the working electrode, we demonstrate the growth and morphology control of Cu and Cu2O through the electrodeposition technique, which is not accessible by using conventional ITO electrodes. The oxidation state of the copper species electrodeposited on PANI surfaces can be manipulated from zero-valent copper (Cu) to cuprous oxide (Cu2O) simply by changing the copper precursors, where Cu2O can be obtained from copper salts of weak acid (copper acetate, copper gluconate), and copper salts of strong acid such as copper sulfate and copper nitrate lead to Cu. Besides, the morphology evolution of Cu and Cu2O has been carefully studied by time-dependent scanning electron microscopy. We believe this oxidation state selection (cuprous oxide or copper) on conducting polymer surfaces can be applied in the synthesis of other materials.

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