文献类型： 外文期刊

作者： Wan, Ming-Jie ¹ ; Wu, Yu-Ting ¹ ; Wang, Yan-Hui ¹ ; Wu, Xiao-Hang ² ; You, En-Ming ³ ; Wang, An ¹ ; Liu, Sheng-Hong ⁴ ; Chen, Jin-Chao ⁵ ; Zhang, Yue-Jiao ² ; Jin, Shangzhong ¹ ; Zhang, Fan-Li ¹ ;

作者机构： 1.China Jiliang Univ, Coll Opt & Elect Technol, Hangzhou 310018, Peoples R China

2.Xiamen Univ, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China

3.Jimei Univ, Sch Ocean Informat Engn, Xiamen 361021, Peoples R China

4.Xinjiang Acad Agr Sci, Inst Agr Qual Stand & Testing Technol, Urumqi 830091, Peoples R China

5.Zhejiang Canc Hosp, Dept Urol Surg, Hangzhou 310005, Peoples R China

关键词： Surface-enhanced Raman scattering; Magnetical plasmonic nanostructure; Pesticide residues detection; Raman internal standard; Quantitative analysis

期刊名称：FOOD CHEMISTRY （ 影响因子：9.8； 五年影响因子：9.7 ）

ISSN： 0308-8146

年卷期： 2025 年 492 卷

页码：

收录情况： SCI

摘要： Pesticide application ensures the yield of crops and reduces the harm of pathogenic microorganisms to the human body. However, excessive use of pesticides leads to their residues on the surface of foods, thus posing a threat to human health and the ecological environment. Herein, Fe3O4@Au@1,4-BDT@Au nanoparticle, as a novel three-dimensional surface-enhanced Raman scattering (SERS) substrate, was constructed enabling the rapid and quantitative detection of pesticide residues of food surfaces combined with a portable Raman spectrometer, which integrates the advantages of multiple components, such as magnetic effect enrichment, Raman internal standard, and strong electromagnetic fields via coupling of gold nanoparticles. In practical detection, the limit of quantitation (LOQ) of thiram and malachite green are 2.5 x 10- 7 M and 10-10 M, respectively. Furthermore, the proportion of mixed pesticides is determined by principal component analysis (PCA), which provides an effective solution for the simultaneous detection of multiple pesticide residues in complex detection conditions.