Determination of Sulfonylurea Herbicides in Grain Samples by Matrix Solid-Phase Dispersion with Mesoporous Structured Molecularly Imprinted Polymer
文献类型： 外文期刊
作者： Liang, Ting 1 ; Gao, Lei 2 ; Qin, Dongli 2 ; Chen, Ligang 1 ;
作者机构： 1.Northeast Forestry Univ, Coll Sci, Dept Chem, 26 Hexing Rd, Harbin 150040, Heilongjiang, Peoples R China
2.Chinese Acad Fishery Sci, Heilongjiang River Fisheries Res Inst, 232 Hesong St, Harbin 150070, Heilongjiang, Peoples R China
关键词： Molecularly imprinted polymers; Mesoporous silica materials; Matrix solid-phase dispersion; Sulfonylurea herbicides; Grain; Liquid chromatography-tandem mass spectrometry
期刊名称：FOOD ANALYTICAL METHODS （ 影响因子：3.366； 五年影响因子：3.07 ）
ISSN： 1936-9751
年卷期： 2019 年 12 卷 9 期
页码：
收录情况： SCI
摘要： A method for determination of sulfonylurea herbicides (SUHs) in grain was developed by using mesoporous structured molecularly imprinted polymers (M-MIPs) as adsorbents of matrix solid-phase dispersion (MSPD) extraction, coupled with liquid chromatography-tandem mass spectrometry (LC-MS/MS). In this method, M-MIPs were synthesized by selecting chlorimuron-ethyl as template molecule, cetyltrimethylammonium bromide as mesoporous structure directing agent, 3-aminopropyltriethoxysilane as functional monomer, and tetraethyl orthosilicate as crosslinker. Then, M-MIPs were characterized by diverse instrumental techniques, absorption characteristics of M-MIPs were studied, and the experimental conditions for the MSPD extraction were optimized. MSPD enabled extraction and clean-up steps to be completed simultaneously. The M-MIPs with mesoporous structure improved detection selectivity, increased adsorptive capacity, and accelerated adsorption rate. Under the best conditions, excellent linearity of SUHs was obtained in the range of 0.25-25 mu g kg(-1), the determination limits of chlorimuron-ethyl, nicosulfuron, thifensulfuron-methyl and chlorsulfuron were 0.075, 0.069, 0.083, and 0.105 mu g kg(-1), respectively. The relative standard deviations were less than 5.5%.
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