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Is addition of reductive metals (Mo, W) a panacea for accelerating transition metals-mediated peroxymonosulfate activation?

文献类型： 外文期刊

作者： Sheng, Bo 1 ; Zhou, Xin 2 ; Shi, Zhun 2 ; Wang, Zhaohui 3 ; Guo, Yaoguang 1 ; Lou, Xiaoyi 5 ; Liu, Jianshe 2 ;

作者机构： 1.Shanghai Polytech Univ, Sch Environm & Mat Engn, Res Ctr Resource Recycling Sci & Engn, Shanghai 201209, Peoples R China

2.Donghua Univ, Coll Environm Sci & Engn, State Environm Protect Engn Ctr Pollut Treatment, Shanghai 201620, Peoples R China

3.East China Normal Univ, Shanghai Key Lab Urban Ecol Proc & Ecorestorat, Sch Ecol & Environm Sci, Shanghai 200241, Peoples R China

4.Inst Ecochongming IEC, 20 Cuiniao Rd, Shanghai 202162, Peoples R China

5.Chinese Acad Fishery Sci, East China Sea Fisheries Res Inst, Key Lab Control Qual & Safety Aquat Prod, Minist Agr, Shanghai 200090, Peoples R China

6.Shanghai Inst Pollut Control & Ecol Secur, Shanghai 200092, Peoples R China

关键词： Sulfate radical; Molybdenum; Transition metal ions; Peroxymonosulfate; Redox cycling

期刊名称：JOURNAL OF HAZARDOUS MATERIALS （ 影响因子：10.588； 五年影响因子：10.129 ）

ISSN： 0304-3894

年卷期： 2020 年 386 卷

页码：

收录情况： SCI

摘要： The interaction of reductive metal ions and peroxymonosulfate (PMS) is necessary for the generation of sulfate radials (SO4 center dot-), however, this process is greatly restrained by the sluggish reduction of high-valent metal ions. Here we report that commercially available reductive metal (Mo or W) powders are capable of unlocking this kinetic constraint. The reduction of Fe(III) to Fe(II), decomposition of PMS, and degradation/mineralization of 4-chlorophenol (4-CP) are all accelerated in the Mo/Fe2+/PMS process at a very low Fe2+/PMS ratio (Fe2+/PMS = 1/10). In such an accelerated system, common adverse effects of natural water constituents such as chloride and humic acid are largely mitigated. According to the fluorescence measurement and scavenging tests, sulfate and hydroxyl radicals dominate in Mo/Fe2+/PMS process. The addition of Mo or W is further confirmed to favor Cu2+/PMS process, but this is not the case for other metal ions (Mn2+, Ni2+, Ce3+ and Co2+). Reductive zero-valence and four-valence active sites (Mo-0 and Mo4+; W-0 and W4+) play key roles in overall redox reaction. Overall, our present work provides an alternative route for expediting redox cycling of transition metals in advanced oxidation processes, without useless consumption of PMS and increase of total organic carbon.

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