文献类型： 外文期刊

作者： Wang, Huifeng ¹ ; Gao, Yuan ³ ; Hu, Wenyou ² ; Wu, Qiumei ² ; Zhong, Xinling ¹ ; Huang, Biao ² ; Hu, Xiaojun ¹ ; Wu, Chunjiang ⁴ ;

作者机构： 1.Shanghai Inst Technol, Shanghai 201418, Peoples R China

2.Chinese Acad Sci, Inst Soil Sci, Key Lab Soil Environm & Pollut Remediat, Nanjing 210008, Peoples R China

3.Shanghai Acad Agr Sci, Ecoenvironm Protect Res Inst, Shanghai 201403, Peoples R China

4.Jiangsu Longchang Chem Co Ltd, Nantong 226500, Peoples R China

关键词： Agricultural soil; Bioavailability; Cadmium immobilization; Food security

期刊名称：AGRICULTURE ECOSYSTEMS & ENVIRONMENT （ 影响因子：6.6； 五年影响因子：6.7 ）

ISSN： 0167-8809

年卷期： 2023 年 356 卷

页码：

收录情况： SCI

摘要： The green development of stabilizers is an important part of soil health management. Studying the impact of stabilizers on soil cadmium (Cd) adsorption is critical for sustainable agriculture. Calcium-aluminum layered double hydroxides (Ca-Al-LDH) are widely used to detoxify contaminated water and soil. Nevertheless, little is known about the efficacy of Ca-Al-LDH at modulating the heavy metal bioavailability of various crops. Incu-bation experiments, greenhouse and 3-year field trials were conducted to investigate the effects of Ca-Al-LDH on Cd, lead (Pb), and zinc (Zn) bioavailability in different soil-crop systems. The main soil type was hydragric anthrosols. The results showed that Ca-Al-LDH remediate heavy metal pollution through surface complexation, surface precipitation, and metal cation exchange with alkali. In incubation experiments, the application of 3 % Ca-Al-LDH for 7-42 d significantly decreased soil CaCl2-extractable Cd, Zn, and Pb by 94.38-96.37 %, 77.90-94.22 %, and 7.23-56.79 %, respectively, relative to the control (p < 0.05). It significantly lowered the exchangeable Cd fraction while increasing the carbonate-bound and the iron-manganese oxide-bound Cd frac-tions in the incubation and pot experiments. It significantly reduced the Cd content in bioaccumulator crops such as spinach, celery, amaranth, Shanghai bok choy, and lettuce-an. The Cd content in low-Cd-accumulation veg-etables, such as bok choy, swamp cabbage, and lettuce-ra, increased following Ca-Al-LDH treatment to soil. Ca-Al-LDH activity remained stable for 3 years. The present study demonstrated that Ca-Al-LDH is a highly effective, sustainable, and versatile amendment for planting high-Cd vegetable cultivars. However, it should be avoided in areas with low Cd contamination or cautiously used when growing vegetables with low Cd-accumulation. It provides a theoretical and practical foundation for evaluating stabilizers and soil health management to reme-diate Cd-contaminated agricultural soils.