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Simultaneous Determination of Organophosphate Ester Flame Retardants in Water and Sediments by Gas Chromatography-Tandem Mass Spectrometry (GC-MS/MS)

文献类型： 外文期刊

作者： Zeng, Yimei 1 ; Ke, Changliang 2 ; Liu, Qi 2 ; Huang, Ke 2 ;

作者机构： 1.Shanghai Ocean Univ, Coll Food Sci, Shanghai, Peoples R China

2.Chinese Acad Fishery Sci, South China Sea Fisheries Res Inst, Guangzhou, Peoples R China

3.Minist Agr & Rural Affairs, Key Lab Aquat Prod Proc, Guangzhou, Peoples R China

4.Guangdong Prov Key Lab Fishery Ecol & Environm, Guangzhou, Peoples R China

关键词： Aquaculture; gas chromatography-tandem mass spectrometry (GC-MS; MS); organophosphate ester; sediments; water

期刊名称：ANALYTICAL LETTERS （ 影响因子：2.267； 五年影响因子：1.823 ）

ISSN： 0003-2719

年卷期：

页码：

收录情况： SCI

摘要： Organophosphate esters (OPEs) are commonly used in commercial products as flame retardants. In the present study, a simple method was established for the simultaneous determination of 10 OPEs in aquacultural water and sediments. The targets were extracted using dichloromethane or ethyl acetate, cleaned up by solid-phase extraction, and determined by gas chromatography - tandem mass spectrometry. The matrix effects were lower than 20% for all OPEs except for tris(2-chloroethyl) phosphate in sediments (matrix effect: 29.4%). In spiked water samples, the recoveries of the OPEs were from 72.3% to 108% with relative standard deviations <= 10.2% and the limits of detection from 0.17 to 1.13 ng center dot L-1. In spiked sediments, the recoveries of the OPEs were from 101% to 121% with relative standard deviations <= 11.2% with limits of detection from 0.02 to 0.32 ng center dot g(-1), dry weight (dw). The developed method was applied to the analysis of aquaculture samples from Kaozhouyang Bay, China. The total concentration ranges of the 10 OPEs in the water and sediments were from 121 to 159 ng center dot L-1 and 7.54 to 13.3 ng center dot g(-1), dw, respectively.

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