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Degradation behavior of a proton exchange membrane fuel cell stack under dynamic cycles between idling and rated condition

文献类型： 外文期刊

作者： Wang, Guangjin 1 ; Huang, Fei 2 ; Yu, Yi 3 ; Wen, Sheng 1 ; Tu, Zhengkai 4 ;

作者机构： 1.Hubei Engn Univ, Coll Chem & Mat Sci, Xiaogan 43200, Peoples R China

2.Guangdong Acad Agr Sci, Sericultural & Agrifood Res Inst, Key Lab Funct Foods, Guangdong Key Lab Agr Prod Proc,Minist Agr, Guangzhou 510610, Guangdong, Peoples R China

3.SAIC Motor, Res & Adv Technol Dept, Shanghai 201804, Peoples R China

4.Huazhong Univ Sci & Technol, Sch Energy & Power Engn, Wuhan 430074, Hubei, Peoples R China

关键词： Proton-exchange membrane fuel cell; Idling condition; Rated condition; High-frequency resistance

期刊名称：INTERNATIONAL JOURNAL OF HYDROGEN ENERGY （ 影响因子：5.816； 五年影响因子：5.242 ）

ISSN： 0360-3199

年卷期： 2018 年 43 卷 9 期

页码：

收录情况： SCI

摘要： The durability of proton exchange membrane (PEM) fuel cells is a key factor which prevents its commercial application on the vehicle. Dynamic current cycle is one of the most common conditions for PEM fuel cells, especially varying the currents between the idling and the rated condition. To investigate the degradation behavior of fuel cells under this kind of dynamic cycles, a PEM fuel cell stack with 330 cm(2) active area is operated under 10,000 dynamic cycles with the cycling current density ranging from 25 mAcm(-2) to 600 mAcm(-2), which simulates common operating conditions in a vehicle cycle from the idling condition to the rated condition. Polarization curves, the high-frequency resistance (HFR), the uniformity of the individual cells, the performance degradation of PEM fuel cell stack at 25 mAcm(-2) and 600 mAcm(-2) are characterized to investigate the performance degradation over cycling. In addition, scanning electron microscopy (SEM) of the surface and the cross-section of the tested membrane electrode assemblies (MEAs) are compared with different single-cell samples. The results indicate that the degradation rate of the stack is 1.0 mu Vcycle(-1) at 25 mAcm(-2) under the idling condition. A more severe performance degradation of about 2.0 mu Vcycle(-1) is detected at 600 mAcm(-2) under the rated condition. The individual cell near the coolant outlet of the PEM fuel cell stack shows a more serious degradation caused by the HFR increase, which is also proved by the SEM analysis. The cross-section SEM analysis indicates that the dynamic cycle has a significantly negative effect on the catalyst layer, resulted in an obvious decrease on the thickness of the catalyst layer. (C) 2018 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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